This invention relates to the field of water-
soluble polymer materials technology, and discloses a comb-shaped ternary
polymer and its preparation process. The
polyacrylamide is polymerized from a backbone
monomer, anionic
monomer, comb-shaped macromolecular
monomer, and optional functional reinforcing monomers under the action of a
redox and azo-based composite
initiation system. The preparation process includes solution preparation and
neutralization,
deoxygenation and
temperature control, adiabatic
polymerization, and post-treatment steps, employing a control strategy combining low-temperature
initiation and adiabatic temperature rise
polymerization. This invention effectively overcomes the defects of traditional linear polymers—low
viscosity retention and poor
shear resistance—in high-temperature and high-salt environments by introducing comb-shaped side chains to create a steric hindrance effect. The resulting product possesses ultra-high molecular weight, low water-insoluble content, and excellent
solubility, exhibiting excellent salt-resistant thickening advantages and
mechanical stability, meeting the
oil displacement requirements of harsh reservoir environments.