The present application relates to the technical field of rubber sealing material, and particularly relates to a modified
fluorine rubber, a preparation method thereof and a
semiconductor sealing
assembly. The preparation method provided by the present application comprises the following steps: mixing vinylidene
fluoride,
hexafluoropropylene,
tetrafluoroethylene, long-chain modified flexible monomers and
vulcanization point monomers in a predetermined proportion to obtain mixed monomers; mixing the mixed monomers, a
solvent and a
fluorine-containing surfactant, and then performing first stirring treatment to obtain a
monomer pre-
emulsion; mixing the
monomer pre-
emulsion, an additive and the
solvent, and then performing second stirring treatment to obtain a product to be treated; placing the product to be treated at a first temperature, heating to a second temperature under predetermined conditions, and then performing reaction to obtain a
reaction product; recovering the mixed monomers that do not participate in the reaction in the
reaction product, adding a
magnesium nitrate aqueous solution, performing third stirring treatment, and then
drying to obtain the modified
fluorine rubber. Under the premise of maintaining the excellent
chemical resistance of the fluorine rubber, the present application significantly improves the elastic
recovery performance of the fluorine rubber in a wide temperature range.