The invention relates to a process and device for recycling dimethyl carbonate through a steam permeation method. The process comprises the specific steps that some byproducts are removed after a reaction solution is subjected to primary distillation, and a methanol-dimethyl carbonate azeotrope enters an extractive distillation tower from the middle and makes contact with spraying water on the top of the tower for extractive separation; methyl alcohol is separated out of liquid at the bottom of the extractive tower through a steam permeable membrane, water and trace dimethyl carbonate are retuned to the top of the extractive tower after being subjected to heat exchange, distillate on the top of the extractive tower is separated through a separator, the water layer at the bottom of the separator returns to the extractive tower, the organic matter layer on the upper portion of the separator is further heated to enter the steam permeable membrane, high-concentration dimethyl carbonate is separated out through the separator, the dimethyl carbonate enters a dimethyl carbonate storage pot after being condensed through a condenser, and permeable water returns to the top of the tower after being subjected to heat exchange. The process and device have the advantages that the technological process is simple, the safety coefficient is high, equipment investment is low, the energy utilization rate is high, and the recycling rate is high.