The invention relates to a process and device for recycling
dimethyl carbonate through a steam
permeation method. The process comprises the specific steps that some byproducts are removed after a reaction solution is subjected to primary
distillation, and a
methanol-
dimethyl carbonate azeotrope enters an
extractive distillation tower from the middle and makes contact with spraying water on the top of the
tower for extractive separation; methyl
alcohol is separated out of liquid at the bottom of the extractive
tower through a steam permeable membrane, water and trace
dimethyl carbonate are retuned to the top of the extractive tower after being subjected to heat exchange, distillate on the top of the extractive tower is separated through a separator, the
water layer at the bottom of the separator returns to the extractive tower, the
organic matter layer on the upper portion of the separator is further heated to enter the steam permeable membrane, high-concentration dimethyl
carbonate is separated out through the separator, the dimethyl
carbonate enters a dimethyl
carbonate storage pot after being condensed through a condenser, and permeable water returns to the top of the tower after being subjected to heat exchange. The process and device have the advantages that the technological process is simple, the
safety coefficient is high, equipment investment is low, the energy
utilization rate is high, and the recycling rate is high.