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33results about How to "Reduce membrane area" patented technology

Process and device for recycling dimethyl carbonate through steam permeation method

The invention relates to a process and device for recycling dimethyl carbonate through a steam permeation method. The process comprises the specific steps that some byproducts are removed after a reaction solution is subjected to primary distillation, and a methanol-dimethyl carbonate azeotrope enters an extractive distillation tower from the middle and makes contact with spraying water on the top of the tower for extractive separation; methyl alcohol is separated out of liquid at the bottom of the extractive tower through a steam permeable membrane, water and trace dimethyl carbonate are retuned to the top of the extractive tower after being subjected to heat exchange, distillate on the top of the extractive tower is separated through a separator, the water layer at the bottom of the separator returns to the extractive tower, the organic matter layer on the upper portion of the separator is further heated to enter the steam permeable membrane, high-concentration dimethyl carbonate is separated out through the separator, the dimethyl carbonate enters a dimethyl carbonate storage pot after being condensed through a condenser, and permeable water returns to the top of the tower after being subjected to heat exchange. The process and device have the advantages that the technological process is simple, the safety coefficient is high, equipment investment is low, the energy utilization rate is high, and the recycling rate is high.
Owner:NANJING UNIV OF TECH

Method for producing vitamin C by esterification reaction-infiltration evaporation barrier separation integral process

The present invention provides a method of synthesizing the vitamin C (V C ) through the esterification, the pervaporation (PV) membrane separation and integration technology, comprising the process of the methyl esterification between the methanol and the 2-ketone-L-gulonic acid (2-KLG) to produce the 2-ketone-L-gulonic methyl ester (2-Me-KLG). The process comprises the following steps: (1) the solid or liquid 2-KLG is dissolved in the methanol; the temperature is then raised and the catalyst is added; (2) the reaction solution prepared in the first step is pumped into the PV membrane separation device; the reaction solution after the membrane dehydration circulates into the esterification reactor; (3) the product 2-Me-KLG or the reaction solution is directly provided for the later production of the VC. In the method of the present invention, the area of the used membrane is small; the ratio between the alcohol and acid of the raw material liquid and the reaction temperature are relatively low; the invention greatly improves the purity and collection rate of the 2-Me-KLG; the technology is simple and the process is stable; the present invention is suitable for the industrial production-line.
Owner:ZHEJIANG GONGSHANG UNIVERSITY

Crosslinked, thermally rearranged poly(benzoxazole-co-imide), gas separation membranes comprising the same and preparation method thereof

The present disclosure relates to a crosslinked, thermally rearranged poly(benzoxazole-co-imide) copolymer membrane prepared simply by heat-treating a membrane prepared from an o-hydroxypolyimide copolymer having carboxylic acid groups such that thermal crosslinking and thermal rearrangement occur simultaneously or a gas separation membrane containing a crosslinked, thermally rearranged poly(benzoxazole-co-imide) copolymer having a benzoxazole group content of less than 80% in the polymer chain, prepared from transesterification crosslinking of an o-hydroxypolyimide copolymer having carboxylic acid groups and a diol-based compound followed by thermal rearrangement, and a method for preparing the same (a membrane for flue gas separation is excluded).In accordance with the present disclosure, a crosslinked, thermally rearranged poly(benzoxazole-co-imide) copolymer membrane for gas separation can be prepared simply through heat treatment without requiring a complicated process such as chemical crosslinking, UV irradiation, etc. for forming a crosslinked structure and a gas separation membrane (a membrane for flue gas separation is excluded) prepared therefrom exhibits superior permeability and selectivity. Also, the method is applicable to commercial-scale production because the preparation process is simple.
Owner:IUCF HYU (IND UNIV COOP FOUND HANYANG UNIV)

Membranes for flue gas separation comprising crosslinked, thermally rearranged poly(benzoxazole-co-imide) and preparation method thereof

The present disclosure relates to a membrane for flue gas separation containing a crosslinked, thermally rearranged poly(benzoxazole-co-imide) copolymer prepared simply by heat-treating a membrane prepared from an o-hydroxypolyimide copolymer having carboxylic acid groups such that thermal crosslinking and thermal rearrangement occur simultaneously or a membrane for flue gas separation containing a crosslinked, thermally rearranged poly(benzoxazole-co-imide) copolymer having a benzoxazole group content of less than 80% in the polymer chain, prepared from transesterification crosslinking of an o-hydroxypolyimide copolymer having carboxylic acid groups and a diol-based compound followed by thermal rearrangement, and a method for preparing the same.In accordance with the present disclosure, a crosslinked, thermally rearranged poly(benzoxazole-co-imide) copolymer membrane for flue gas separation can be prepared simply through heat treatment without requiring a complicated process such as chemical crosslinking, UV irradiation, etc. for forming a crosslinked structure and a membrane for flue gas separation prepared therefrom exhibits superior permeability and selectivity. Also, the method is applicable to commercial-scale production because the preparation process is simple.
Owner:IUCF HYU (IND UNIV COOP FOUND HANYANG UNIV)

Membranes for flue gas separation comprising crosslinked, thermally rearranged poly(benzoxazole-co-imide) and preparation method thereof

The present disclosure relates to a membrane for flue gas separation containing a crosslinked, thermally rearranged poly(benzoxazole-co-imide) copolymer prepared simply by heat-treating a membrane prepared from an o-hydroxypolyimide copolymer having carboxylic acid groups such that thermal crosslinking and thermal rearrangement occur simultaneously or a membrane for flue gas separation containing a crosslinked, thermally rearranged poly(benzoxazole-co-imide) copolymer having a benzoxazole group content of less than 80% in the polymer chain, prepared from transesterification crosslinking of an o-hydroxypolyimide copolymer having carboxylic acid groups and a diol-based compound followed by thermal rearrangement, and a method for preparing the same.In accordance with the present disclosure, a crosslinked, thermally rearranged poly(benzoxazole-co-imide) copolymer membrane for flue gas separation can be prepared simply through heat treatment without requiring a complicated process such as chemical crosslinking, UV irradiation, etc. for forming a crosslinked structure and a membrane for flue gas separation prepared therefrom exhibits superior permeability and selectivity. Also, the method is applicable to commercial-scale production because the preparation process is simple.
Owner:IUCF HYU (IND UNIV COOP FOUND HANYANG UNIV)

Method for producing vitamin C by esterification reaction-infiltration evaporation barrier separation integral process

The present invention provides a method of synthesizing the vitamin C (V C ) through the esterification, the pervaporation (PV) membrane separation and integration technology, comprisingthe process of the methyl esterification between the methanol and the 2-ketone-L-gulonic acid (2-KLG) to produce the 2-ketone-L-gulonic methyl ester (2-Me-KLG). The process comprises the following steps: (1) the solid or liquid 2-KLG is dissolved in the methanol; the temperature is then raised and the catalyst is added; (2) the reaction solution prepared in the first step is pumped into the PV membrane separation device; the reaction solution after the membrane dehydration circulates into the esterification reactor; (3) the product 2-Me-KLG or the reaction solution is directly provided for the later production of the VC. In the method of the present invention, the area of the used membrane is small; the ratio between the alcohol and acid of the raw material liquid and the reaction temperature are relatively low; the invention greatly improves the purity and collection rate of the 2-Me-KLG; the technology is simple and the process is stable; the present invention is suitablefor the industrial production-line.
Owner:ZHEJIANG GONGSHANG UNIVERSITY
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