The invention provides a measurement method for a dense non-aqueous phase liquid (DNAPL) and aqueous phase interfacial area. According to the method, by measuring the saturability and dissolution rate of DNAPL, and utilizing the relation between the interfacial area and the saturability and dissolution rate of the DNAPL, the interfacial area values are obtained. The two interfacial area values are endowed with set weighted values respectively, the weights are reckoned in the obtained interfacial area values respectively, a final interfacial area value is calculated, and a more precise area value is obtained. The migration distribution status of the DNAPL in underground water is objectively reflected, a decision maker is helped to select an optimal organic-contaminated groundwater repairing method. The method is simple and convenient to practice, maneuverability is high, the experimental period is shortened, and the problems of economic and time cost caused by a traditional experiment method are effectively solved. According to the technical scheme, the test precision is verified through experiments, and the method is easy to operate indoors, is not limited by complex environment conditions in actual outdoor application and has good application prospects.