The invention discloses a method for catalytically preparing a 4,5-
dihydropyran[c]chromene derivative, and belongs to the technical field of chemical material preparation.In the preparation reaction, the
molar ratio of aromatic
aldehyde to 4-hydroxycoumarin to
malononitrile is 1:1:(1-1.2), the
molar weight of an alkaline
ionic liquid catalyst is 8%-15% of that of aromatic
aldehyde, the volume
dose of a 50%
ethanol water solution serving as reaction
solvent on a milliliter basis is 8-10 times of the
molar weight of aromatic
aldehyde on a millimole basis, the
reflux reaction time ranges from 10 min to 28 min, after the reaction is finished, cooling is conducted to
room temperature, extraction
filtration is conducted, filter residues are washed with ethyl
alcohol and vacuum-dried, and the 4,5-
dihydropyran[c]chromene derivative is obtained.Compared with a preparation method adopting other alkaline
ionic liquid catalysts, the method for catalytically preparing the 4,5-
dihydropyran[c]chromene derivative has the advantages of being high in catalytic activity of the catalyst, free of treatment during the reuse process, high in
raw material utilization rate, easy and convenient to operate in the whole preparation process and the like, and large-scale industrial application is convenient.