41results about How to "Rich synthetic methods" patented technology

The invention discloses a preparation method of a novel carbon-based material loaded transition metal monatomic catalyst, and relates to the field of nano material heterogeneous catalysis. The preparation method comprises the following steps: mixing a DMF solution of a zinc salt and a transition metal salt with a DMF solution of 2-methylimidazole, carrying out heat preservation and centrifugal drying to obtain an M-ZIF-8 precursor, and finally synthesizing the novel carbon-based loaded transition metal monatomic catalyst through synthesis steps of three-step calcination, acid leaching and re-dispersion adsorption. According to the invention, an efficient transition metal monatomic catalyst synthesis method is provided, and the carbon-based material loaded transition metal monatomic catalyst is successfully applied to a reaction system for activating and degrading phenolic compounds by persulfate for the first time; and by taking transition metal Mn as an example, the synthesis method is found to be capable of effectively improving the loading capacity of monatomic metal of the transition metal and efficiently activating persulfate to degrade phenolic compounds, so that a good material basis and a good modification method are provided for application of heterogeneous Fenton-like catalytic reaction in the aspect of wastewater treatment.

The invention discloses a preparation method of a novel zinc monatomic catalyst loaded on a carbon-based material, and relates to the field of nano material heterogeneous catalysis. The preparation method comprises the following steps: mixing a methanol precursor solution composed of cobalt nitrate dissolved by magnetic stirring and 2-methylimidazole, carrying out a magnetic stirring reaction for1 h to obtain a precursor ZIF-8, and subjecting the dried ZIF-8 to calcining and ammoniation to synthesize the zinc monatomic catalyst Zn@NC-1100 DEG C loaded on the carbon-based material. The invention provides a concise zinc monatomic catalyst synthesis method, and a Zn-based material is successfully applied to a persulfate Fenton reaction system for the first time. Meanwhile, the novel zinc monatomic catalyst is high in atom loading capacity and can efficiently catalyze a persulfate Fenton reaction, so that organic pollutants are continuously mineralized. A good material basis and a good modification method are provided for the application of heterogeneous Fenton-like catalytic reaction in the aspect of wastewater treatment.

The invention discloses a synthesis method of a C-3 alkyl substituted coumarin derivative. The synthesis method comprises the following steps: dissolving a coumarin derivative shown as a formula (I),an N-alkyloxyphthalimide compound shown as a formula (II), a photocatalyst and a proton acid in an organic solvent; reacting under visible light irradiation at a temperature of 20 to 60 DEG C for 3 to36 hours; after the reaction is finished, performing post-treatment on a reaction system to obtain a target product of the C-3 alkyl substituted coumarin derivative shown as a formula (III), whereinthe reaction formulas are shown in the description; in the formulas (I) and the formula (III), the substituent R1 is H, methyl, methoxy, fluorine, chlorine or bromine; in the formula (II) and the formula (III), the substituent R2 is linear alkyl or naphthenic alkyl of with 1 to 8 carbon atoms. The synthesis method realizes the C-3alkylation of coumarin with light as reaction energy, makes the reaction safer, more environmentally friendly and cheaper, expands the application range of the reaction substrate, and enriches the synthesis method of a C-3 substituted coumarin compound.

The invention relates to a naphtho- / anthra-pyrazole derivative and a synthetic method thereof. The structure of a compound is shown in the specifications, wherein X is OCH3, CH3, H, Cl or NO2. The naphtho- / anthra-pyrazole derivative is synthesized through twice cycloaddition reactions and a deoxygenization reaction, the requirement of an atom economy reaction is met, a brand new thought is provided for the establishment of a naphtho- / anthra-pyrazole framework, and a synthetic method of an organic heterocyclic compound is enriched. The synthetic method of the naphtho- / anthra-pyrazole derivative disclosed by the invention is not reported yet.

The invention discloses a preparation method of a benzodithiocyclopentadiene derivative. Benzodithiocyclopentadiene is synthesized by reacting S8 as a sulfur source with 2-bromothioamide. The synthesis method provides a cheap, easily available and environment-friendly synthesis method for synthesis of benzodithiocyclopentadiene compounds, adopts a green and environment-friendly reaction system, obtains products easy to be separated and purified, is suitable for synthesizing various highly functionalized benzodithiocyclopentadiene compounds, is particularly suitable for large-scale industrial production, and can prepare high-purity benzodithiocyclopentadiene compounds at high efficiency and high yield.

The present invention provides a kind of preparation method of oxamide, and this preparation method comprises the following steps: with CO, O 2 and amine compounds as raw materials, under the action of catalyst 1, oxidative carbonylation to prepare intermediate oxamide derivatives, and then under the action of catalyst 2, aminolysis of oxamide derivatives to prepare oxamide. The invention uses a brand-new method to co-produce oxamide and oxamide derivatives, which solves the problems of toxic oxalate synthesis raw materials and low catalyst efficiency in the original technology of synthesizing oxamide through aminolysis of oxalate. In addition, the process for synthesizing oxamide derivatives has good substrate applicability and can be used in fields such as medicine, pesticides, synthetic ligands, and food additives.

The invention discloses a method for preparing anthraquinone by an anthracene oxidation method using a starch modified catalyst, using γ-Al 2 O 3 As the carrier, Fe and Zr oxides are the active components, and Fe‑γ‑Al is prepared by equal volume impregnation method. 2 O 3 , Zr‑γ‑Al 2 O 3 Single supported catalyst and Fe‑Zr / γ‑Al 2 O 3 Dual-loaded catalyst, modified carrier according to the mass ratio of starch: carrier = 1:100, while using starch modified carrier to prepare a series of modified catalysts. Ultra-high performance liquid chromatography was used to analyze the product, the catalytic performance of the catalyst in the reaction of anthracene oxidation to synthesize anthraquinone was analyzed, and XRD and other means were used to characterize the catalyst.

The invention discloses a preparation method of a benzodithiocyclopentadiene derivative. Benzodithiocyclopentadiene is synthesized by reacting S8 as a sulfur source with 2-bromothioamide. The synthesis method provides a cheap, easily available and environment-friendly synthesis method for synthesis of benzodithiocyclopentadiene compounds, adopts a green and environment-friendly reaction system, obtains products easy to be separated and purified, is suitable for synthesizing various highly functionalized benzodithiocyclopentadiene compounds, is particularly suitable for large-scale industrial production, and can prepare high-purity benzodithiocyclopentadiene compounds at high efficiency and high yield.

The invention discloses C 3 N 4 The synthesis method, product and application of quantum dot room temperature phosphorescent material. The synthesis method is to use urea or other urea-like small molecules as raw materials, and carry out high-temperature solid-phase reaction in a high-pressure reactor. The obtained product is gray-white powder with solid-phase fluorescence. At the same time, it can continuously emit blue-green phosphorescence visible to the naked eye for 3-6s at room temperature; its preparation method is simple, does not contain harmful metals, and is a new type of room temperature phosphorescent material; it has potential in 3D printing, anti-counterfeiting, decoration, imaging and other fields application value.

The invention discloses a synthesis method of C-3 alkyl-substituted coumarin derivatives, which combines the coumarin derivatives represented by the formula (I), the coumarin derivatives represented by the formula (II) N ‑alkanoyloxyphthalimide compound, photocatalyst and protonic acid are dissolved in an organic solvent, and reacted at 20‑60°C for 3‑36 h under visible light irradiation. After the reaction, the reaction system After post-processing, the C-3 alkyl-substituted coumarin derivative target product shown in formula (III) is obtained; the reaction formula is as follows: In formula (I) and formula (III), the substituent R 1 Is H, methyl, methoxy, fluorine, chlorine or bromine; in formula (II) and formula (III), substituent R 2 It is C1-C8 linear alkyl or cycloalkyl. The invention realizes the C-3 alkylation of coumarin by using light as the reaction energy, makes the reaction safer, greener, and lower in cost, expands the scope of application of the substrate of the reaction, and enriches the coumarins substituted by C-3 Compound synthesis method.

The invention discloses a synthesis method of a C-3-position difluoromethyl-substituted quinoxalinone derivative. The method comprises the steps of dissolving a quinoxalinone derivative, a bromodifluoromethyl compound, a photocatalyst, an inorganic base and an organic amine in an organic solvent for a reaction for 6-36 hours at the temperature of 20-60 DEG C under the irradiation of visible light;after the reaction is finished, carrying out posttreatment on a reaction system to obtain a target product, namely the C-3-position difluoromethyl-substituted quinoxalinone derivative. According to the method, light is adopted as a reaction energy source to realize C-3 difluoro methylation of quinoxalinone, so that the reaction is safer, environmentally friendly and lower in cost, the applicationrange of reaction substrates is expanded, and synthesis methods of C-3 substituted quinoxalinone compounds are diversified.

The present application discloses a table edge surround material, the raw materials of which include by weight: 80-120 parts of thermoplastic polyurethane elastomer, 40-50 parts of polyvinyl chloride, 20-60 parts of polytetrafluoroethylene, 5-5 parts of potassium sodium silicate 15 parts, 4-8 parts of blue alum, 3-9 parts of short polyester fiber, 4-8 parts of long glass fiber, 2-8 parts of nano calcium carbonate, 10-20 parts of wear-resistant enhancer, 4-8 parts of chain extender 15-25 parts of modified reinforcing agent A, 16-32 parts of modified reinforcing agent B. The present invention also proposes a preparation method of the above-mentioned table edge surrounding material. The table edge surround material prepared by the invention has excellent wear resistance, strength and toughness.

A method for preparing a macro-monomer synthesized polycarboxylate water reducer through alcoholysis of alkenyl-acyl chloride belongs to the field of water reducers. The method comprises the following steps: firstly polymerizing a cationic chain, and then reacting with the alkenyl-acyl chloride, thus obtaining a macro-monomer; then carrying out copolymerization on the macro-monomer and a carboxylic acid micro-monomer, i.e., polymerizing under an oxidization-reduction initiating system formed by high-valence cerate and alcohols by taking an unsaturated cationic quaternary ammonium salt monomer as a reactant, thus obtaining a terminal hydroxyl cationic long chain; then respectively enabling the terminal hydroxyl cationic long chain and polyethylene glycol monomothyl ether to react with the alkenyl-acyl chloride respectively, thus preparing macro-monomers with different structures; then carrying out free radical polymerization on the macro-monomers and unsaturated carboxylic acid micro-monomers, thus obtaining the macro-monomer composite polycarboxylate water reducer. According to the method disclosed by the invention, the macro-monomers with different structures and functions are successfully synthesized through ways of polymerizing the cationic chain and respectively reacting with the alkenyl-acyl chloride by combining polyether, and a novel comb-structure polycarboxylate water reducer which takes a polycarboxyl acid as a main chain and the cationic long chain and the polyether as polybasic side chains can be finally obtained. A reaction technology is simple and easy, and multiple excellent effects of retaining slump through reducing water, resisting clay, and the like are realized.

The invention discloses a synthesis method of a C3N4 quantum dot room-temperature phosphorescent material and a product and application thereof. The synthesis method comprises the following steps of:taking urea or other urea-like small molecules as raw materials and carrying out a high-temperature solid-phase reaction in a high-pressure reaction kettle to obtain a product which is grey white powder, has solid-phase fluorescence and can continuously emit macroscopic blue-green phosphorescence for 3-6 seconds at room temperature. The preparation method is simple, and the product contains no harmful metal and is a novel room-temperature phosphorescent material; and the C3N4 quantum dot room-temperature phosphorescent material has potential application value in the fields of 3D printing, anti-counterfeiting, decoration, imaging and the like.

The invention relates to a method for preparing an environment-responsive polymer by composite assembly. The present invention uses hydrophobic monomers, polysaccharide derivatives, etc. as the main reaction raw materials, and prepares a magnetic field responsive polymer through the method of first grafting polymerization, cross-linking reaction, and then compound assembly, that is, the hydrophobic monomers are first grafted and polymerized, and then The polysaccharide derivative and ferric iron tetroxide powder are cross-linked under the action of a cross-linking agent to obtain a hydrogel, and finally composite assembled to obtain a magnetic field-responsive polymer. The process of the invention is energy-saving and efficient, and the operation is simple. The magnetic field-responsive polymer is successfully prepared through the method of polysaccharide derivative hydrogel composite assembly of the branch structure polymer, which shows multiple effects such as excellent environmental response and maintaining the stability of the concrete volume, and realizes The goal of self-driven improvement of application performance of concrete materials has very good market competitiveness and application prospects.

The invention relates to a method for preparing octanohydroxamic acid from hydroxylamine sulfate and calcium oxide and belongs to the field of cosmetic raw material synthesis. The method is characterized by comprising the following steps of adding quicklime into a hydroxylamine sulfate solution at a temperature of less than or equal to 10 DEG C, filtering away precipitated calcium sulfate, sequentially adding the quicklime and methyl caprylate, performing hydroxyl oximation reaction at 30-60 DEG C, recovering a solvent after 2-6h, cooling to 0 DEG C, adding 10% hydrochloric acid at the low temperature, regulating a pH (potential of hydrogen) value to 3-4, precipitating octanohydroxamic acid solid, performing filtering, water washing and dryness to form octanohydroxamic acid. The method is mild in reaction condition and high in yield; a product is good in purity; the cheap and readily accessible quicklime is used as alkali, so that the raw material cost is greatly lowered; and the method is applicable to industrial production.

The invention discloses (6-bromo-2,3-difluorobenzyl) phenyl sulfide and a preparation method thereof, the chemical structural formula of (6-bromo-2,3-difluorobenzyl) phenyl sulfide As follows:; The preparation method of (6-bromo-2,3-difluorobenzyl) phenyl sulfide is: 6-bromo-2,3-difluorobenzyl halide and difluorobenzyl halide shown in formula (I) phenylene disulfide is used as a reaction raw material, tetrahydrofuran is used as a solvent, and under the action of a reducing agent and a base, the (6-bromo-2,3-difluorobenzyl) phenyl sulfide is synthesized through a nucleophilic substitution reaction; In formula (I), X represents chlorine, bromine or iodine. The preparation method of (6-bromo-2,3-difluorobenzyl) phenyl sulfide of the present invention has the advantages of high selectivity, high yield, simple operation and the like.

The invention discloses a method for preparing anthraquinone by an anthracene oxidation method, wherein, the catalyst formula: γ-Al 2 o 3 As the carrier, Fe and Zr oxides are the active components, and the Fe-γ-Al is prepared by the equal volume impregnation method 2 o 3 , Zr‑γ‑Al 2 o 3 Single supported catalyst and Fe‑Zr / γ‑Al 2 o 3 dual-supported catalyst. The product was analyzed by ultra-high performance liquid chromatography, and the catalytic performance of the catalyst in the reaction of anthracene oxidation to anthraquinone was analyzed, and the catalyst was characterized by XRD and other means. The present invention attempts to develop a solid-phase catalyst to realize the catalytic oxidation of anthracene to prepare anthraquinone under normal pressure and low temperature (70° C.) conditions, and has the advantages of low energy consumption, low cost, and environmental friendliness.