The invention discloses a method for producing high-water solubility nitrophosphate fertilizer by phosphorite nitrolysis and calcium nitrate freezing. The high-water solubility nitrophosphate fertilizer is prepared from the processes of phosphorite nitrolysis, fluorine removal, calcium nitrate freezing separation, further removal of calcium in ammonium sulfate, ammonia liquor neutralization and deposition removal of impurities, and evaporation concentration and crystallization. Specially, the method for producing high-water solubility nitrophosphate fertilizer by phosphorite nitrolysis and calcium nitrate freezing comprises the following steps of 1, acidolysis, 2, fluorine removal, 3, calcium nitrate freezing crystallization, 4, double decomposition removal of calcium in ammonium sulfate,5, neutralization and deposition removal of impurities, 6, evaporation concentration and crystallization, and 7, phosphogypsum transformation. The high-water solubility nitrophosphate fertilizer prepared by the method has a dissolution rate great than or equal to 99.9% in water, wherein nitrate nitrogen is easy for be absorbed by drops, satisfies requirements of a few commercial crops, has a highutilization rate, and improves a crop yield by 8 to 25% and crop quality. The method reduces waste discharge, is environmentally friendly, can be utilized for structure adjustment and product upgradeand update of the traditional phosphorus chemical industry, and has good economic and environmental benefits.