The invention discloses a peak shaving photovoltaic power station for hydrogen fuel unmanned aerial vehicle operation and maintenance and a working method thereof, and belongs to the technical field of photovoltaic power generation. The peak shaving photovoltaic power station comprises a solar battery pack, a convergence device, an electrolysis device, a hydrogen purification device, a hydrogen compression device, a hydrogen refueling station, a peak regulation fuel battery pack and a hydrogen fuel unmanned aerial vehicle; the solar battery pack is connected with the convergence device, the convergence device is connected with the electrolysis device and an inverter, the hydrogen outlet of the electrolysis device is connected with the hydrogen purification device, the hydrogen purification device is connected with the hydrogen compression device, the hydrogen compression device is connected with the hydrogen refueling station, the hydrogen refueling station is connected with the peak regulation fuel battery pack, and can carry out hydrogenation on the hydrogen fuel unmanned aerial vehicle. The peak shaving photovoltaic power station is high in automation degree, and is energy-saving and environment-friendly, the economic benefits of the power station are improved while the operation and maintenance of the photovoltaic power station are efficient, and the photovoltaic power station has the peak regulation capability.