The invention discloses a production method of a non-developable surface structure of a large bridge steel tower. The method comprises the following steps of: constructing a simplified model of straight line instead of curve according to a curved surface structure by using Solidworks software, preparing a solid body, unfolding the solid body and drawing a curved surface flattening picture; pre-processing a board, blanking, marking out and digging according to the curved surface flattening picture, bending a bending line, detecting a sample plate, and carrying out flame finishing to obtain a split two-dimensional space curved surface; pre-processing the board, blanking, marking out and digging according to a curved surface flattening picture, bending a bending line, detecting a sample plate, carrying out flame finishing, dividing and marking out to carry out multiple divisions, weighting and matching in the field, cutting, assembling and welding to obtain a three-dimensional space curved surface; assembling and welding the split two-dimensional space curved surface and/or the three-dimensional space curved surface in the field, detecting flaw, and coping a welding line. The method provided by the invention is convenient and feasible, the production precise conforms to the design requirements and is simple to operate, hot rolling and a special mould are not adopted, the investment cost is low, and the change and the influence on the mechanical property of a steel material are avoided.