The invention discloses a broadband frequency hopping clustering multistage self-organizing network waveform design method. Distributed centerless multi-hop frequency hopping synchronization, initialnetwork establishment, dynamic gateway selection, physical layer modulation-demodulation and coding-decoding and adaptive routing selection based on link learning are realized. Multi-hop frequency hopping synchronization does not need to preset a synchronization center node and a special frequency hopping frequency set and pattern; wherein the synchronization time is related to the number of frequency points in the frequency hopping frequency set, the frequency hopping rate, the relay hop count and the like; each node transmits a frequency hopping synchronization frame probabilistically according to a local clock and a preset frequency hopping pattern, the nodes are all in a receiving state in other time, after a frame header is captured, the current frequency is kept to receive complete frame data, TOD information and node number information of the received data are obtained, and then synchronization is completed. Due to node movement or external environment change, a multi-hop end-to-end link exists and the link quality also changes, the performance of each link is comprehensively evaluated through a learning strategy, and finally, adaptive routing selection is realized.