The invention relates to a method for electrolyzing high-content low-grade lead bullion. The method comprises the following steps of melting the high-content low-grade lead bullion containing copper, antimony and bismuth into a pot to be stirred for removing the copper, thoroughly removing the copper-containing floating slag, adding alkali to remove arsenic and tin, pumping the lead liquid into an anode plate casting machine to be cast into an anode plate, reasonably matching the use amount of the combined additives to electrolyze the anode plate and the electrolyte according to the chemical components of the anode plate and the chemical components of the electrolyte, extracting cathode lead, washing the cathode lead with water to remove the electrolyte on the surface of the lead and thus obtaining the precipitated lead, casting the refined precipitated lead to obtain lead pig with the quality reaching the No.1 national standard, gathering the antimony, bismuth, copper, gold and silver onto the anode plate to form anode paste, and further comprehensively recovering the antimony, bismuth, copper, gold and silver in balance. By adopting the method, the lead bullion with high contents of copper, antimony and bismuth can be electrolyzed into the qualified precipitated lead in one step, so that the secondary electrolysis cost can be reduced, and the enriched metal grade in the anode paste can be improved.