The invention discloses an ultra-thin, self-supporting, flexible and all-solid-state super capacitor and a manufacturing method of the ultra-thin, self-supporting, flexible and all-solid-state super capacitor. The super capacitor comprises a position electrode, a solid electrolyte and a negative electrode, wherein the solid electrolyte is located between the positive electrode and the negative electrode to separate the positive electrode and the negative electrode, and the solid electrolyte evenly permeates inside a porous structure of the positive electrode and a porous structure of the negative electrode. The positive electrode and the negative electrode are made of carbon nanometer materials or carbon nanometer composite materials, and the outer side of the positive electrode and the outer side of the positive electrode are not completely embedded by the solid electrolyte and can be used for collecting currents. The thickness of the super capacitor is within the range of 10 nanometers to 10 micrometers, the inner portion of the capacitor is provided with no diaphragm, the outer portion of the capacitor needs no metal current collecting electrode or encapsulation, self-supporting can be realized, and at the same time the capacitor has high specific capacitance, high power density, high energy density, long life and high stability. The super capacitor has the advantages of being superior in performance, simple in manufacturing technology, and capable of satisfying the development demands of flexible, miniature, light electronic products at the same time, and having wide application prospects.