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Preparation method of waterborne polyurethane emulsion modified by natural monosaccharide compound

The invention discloses a preparation method of a waterborne polyurethane emulsion modified by a natural monosaccharide compound. The preparation method comprises the following steps: firstly, adding polyglycol to a dry reaction bottle, heating to melt the polyglycol in the reaction bottle and vacuumizing to removal water for 1 hour at 120 DEG C; next, adding a hydrophilic reagent, a chain extender and diisocyanate to the reaction bottle to have a polymerization reaction, thereby obtaining a polyurethane prepolymer; next, adding the natural monosaccharide compound for reacting, cooling after a period of time, and adding an organic base to regulate the pH value of the reaction; and adding deionized water under high speed stirring for emulsifying, and removing the solvent by virtue of reduced pressure distillation, thereby obtaining the waterborne polyurethane emulsion modified by the natural monosaccharide compound. According to the preparation method, the waterborne polyurethane is modified by use of the natural monosaccharide, and the product has excellent overall properties, and also is environment-friendly, harmless, cheap and the like. The coating of the product can be just thermally decomposed at 300 DEG C; compared with the polyurethane before modification, the heat resistance of the modified polyurethane is obviously improved, and meanwhile, the water tolerance of the modified polyurethane is also greatly improved.
Owner:HUIZHOU RES INST OF SUN YAT SEN UNIV
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