The invention discloses a method for preparing 
graphene through electrochemical cathodic disbonding 
graphene sheets by taking DTAB as 
electrolyte. The method is characterized by comprising the following steps: firstly, preparing materials; secondly, preparing electrical disbonding liquor; thirdly, assembling an electrical disbonding device; fourthly, performing electrical disbonding; fifthly, filtering and washing; sixthly, performing 
ultrasonic dispersion; seventhly, performing 
freeze drying, so as to obtain an 
aqueous solution of 
graphene, and performing 
freeze drying, so as to obtain graphene 
powder. The method has the advantages that raw materials for preparation are simple and easy to obtain, the method is easy to operation, the cost is low, the technical process is simple, steps areless, the 
production cycle is short, the defect level of the formed graphene is low, the number of 
layers is small, and the graphene is very suitable for industrial production.