The invention relates to a working electrolyte of a lead aluminum electrolytic capacitor. The working electrolyte is composed of the following raw materials in percentage, by mass of 30-50% of solventI, 10-20% of solvent II, 6-9% of solute I, 2-4% of solute II, 1-3% of antifouling agent, 5-20% of additive and 8-20% of pressure-resistant improver. The preparation method comprises the following steps of adding the solvent I and the solvent II into a reaction kettle, heating while stirring, adding the additive when the temperature rises to 120 DEG C, and continuously heating to 140 DEG C, addingthe solute I and the solute II, keeping the temperature of 140 DEG C for 45 minutes, cooling the kettle to 130 DEG C, adding the pressure-resistant improver, stirring and keeping the temperature for30 minutes, and finally, cooling the kettle to 110 DEG C, adding the antifouling agent, fully stirring, and naturally cooling to room temperature after 45 minutes to obtain the finished product electrolyte. The method is advantaged in that the enough voltage endurance capability can be guaranteed under the condition of high conductivity, the aluminum foil is prevented from hydration reaction, andthe service life of the product is prolonged.