This invention relates to the field of electrochemical technology, and more particularly to a method for testing the reaction
kinetics at the Bi
electrode interface in Li-Bi batteries. The dual-probe measurement
system constructed in this invention works collaboratively on a precise three-dimensional positioning platform of a shared scanning electrochemical
microscope. One probe maps the electrochemical activity distribution on the
electrode surface, visually reflecting the spatial location of low-activity phases, while the other Hg probe simultaneously records the Li content in the corresponding region. + Concentration or
diffusion coefficient. This "functionally complementary, spatially synchronized" measurement mode can integrate observed electrochemical data, interfacial electrochemical activity, and Li... + The migration dynamics are directly related, thus providing experimental evidence for revealing the true rate-limiting steps in the
phase transition process, enabling a more comprehensive and three-
dimensional analysis of complex
electrode processes, and making up for the limitations of single
signal measurement.