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44 results about "Which solvents" patented technology

Process for preparing 2, 3, 5, 6-tetrafluoro-p-xylyl alcohol

The invention discloses a preparation method of 2,3,5,6-tetrafluoro-p-methylbenzyl alcohol, which belongs to the preparation technology of 2,3,5,6-tetrafluoro-p-methylbenzyl alcohol. The method is prepared by taking 2,3,5,6-tetrachloroterephthaloyl chloride as a raw material through fluorination, esterification, reduction, bromination and reduction. The fluorinating agent of the fluorination reaction is potassium fluoride, etc., the solvent is sulfolane, etc., the catalyst is calixarene, etc., and the reaction temperature is 40°C-230°C. Esterification The esterification agent is aliphatic alcohol or aromatic alcohol, and the reaction temperature is 20°C to 120°C. Reduction reaction of ester The reducing agent is sodium borohydride, etc., the solvent is sulfolane, etc., and the reaction temperature is -10°C to 60°C. The bromination agent for the bromination reaction is HBr acid, the solvent is dichloromethane, and the reaction temperature is 30°C to 160°C. The reducing agent of the bromide reduction reaction is magnesium powder, etc., the solvent is fatty alcohol, water, chloride, etc., and the reaction temperature is -10°C to 50°C. The invention has the advantages of simple process, low production cost, high product yield and purity, and is suitable for industrialized production.
Owner:TIANJIN UNIV

Vacuum distillation method and vacuum distillation apparatus

An objective of the present invention is to suppress bumping in the distillation still so as to collect a high purity solvent containing no impurities. A solvent vapor valve 21 is disposed in a solvent vapor withdrawal conduit 20 through which solvent vapor is transferred from inside the distillation still 10 to an inner pipe 31 of a double-tube structure 30 which is a heat exchange section. Also, a thermistor 14 is disposed in an upper space in the distillation still 10. After a heating chamber 11 starts heating the solvent, the start of boiling is determined by a sudden rise in temperature detected by the thermistor 14, and shortly thereafter, the solvent vapor valve 21 is closed to fill the distillation still 10 with the solvent vapor. The solvent vapor actively generated by bumping is condensed and liquefied on the cold inner surfaces of a ceiling wall and a sidewall of the distillation still 10, and concurrently, the heat of condensation is provided to the ceiling wall surface and the sidewall surface, thereby accelerating the temperature rise thereof. Bumping stops when the temperatures of the surfaces of the ceiling wall and the sidewall have reached a sufficiently high temperature, and thereafter the valve 21 is opened to transfer the solvent vapor to the double-tube structure 30 functioning as the heat exchange section.
Owner:SANYO ELECTRIC CO LTD +1
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