The invention discloses a preparation method of
ammonium bifluoride. The preparation method comprises the following steps of: with unsaturated
ammonium fluoride solution with the
mass percent concentration of 10-50% adopted, adding
hydrofluoric acid with the
mass percent concentration of 15-50%, and controlling
reaction temperature to be 40-80 DEG C; after the reaction is finished, adding ammoniasolution with the
mass percent concentration of 12-25% into a
reaction system, reacting with excessive
hydrofluoric acid, controlling
reaction temperature to be below 30 DEG C, reacting for 40-90 minutes, concentrating
ammonium bifluoride solution obtained in a three-opening
bottle, then cooling and crystallizing, so as to obtain
ammonium bifluoride crystals; and
drying the
ammonium bifluoride crystals, thus an
ammonium bifluoride product is obtained. The invention has the beneficial effects that: compared with the prior art, process
route is simple, conditions and requirements are unharsh, and realization is easy; the prepared ammonium
bifluoride product has low
moisture content and high purity, the product does not cake,
energy consumption problem is noticed in a production process of ammonium bifluoride, and excessive consumption of
energy source is avoided. By adopting the preparation method disclosed by the invention,
fluorine resource is efficiently utilized, and the
fluorine resource which enters into a
system is finally converted into the ammonium bifluoride product. The preparation method disclosed by the invention has obvious economic benefit and is applicable to being popularized in
fluorine chemical enterprises.