The invention provides a processing unit for a boiler cleaning connector of a supercritical unit and a cleaning process thereof, belongs to the field of an acid pickling technology, and solves the problems that an existing boiler is bad in acid pickling effect and high in cost. The processing unit for the boiler cleaning connector of the supercritical unit comprises an economizer, a boiler, a steam separator, a water storage tank, a drain flash tank, a drain tank and a wastewater pool, wherein a check valve and a boiler water circulating pump are sequentially connected between the economizer and the water storage tank, the check valve comprises a check valve body with an inlet and an outlet, the check valve body is provided with a first valve cover in which a through hole communicated with an outlet of the check valve body and one end of the through hole extends outwards and protrudes out the check valve body to form a connecting pipe, and the connecting pipe is connected with a washing water pump through a temporary pipeline. The washing process comprises ammonia washing, washing, acid pickling, washing, rinsing and passivating. The processing unit provided by the invention has the advantages of good acid pickling effect and low cost.