The invention discloses a polytropic-process desulfurization device. The device comprises a box body and inclined plates, wherein the inclined plates are fixedly connected to the outer walls of the upper portions of the left side and the right side of the box body, and a desulfurization device is installed in the box body. According to the polytropic-process desulfurization device, through mutualcooperation of structures such as the inclined plates, water pumps, a second vertical plate, a desulfurization tower and a discharging pipe, a solvent can be discharged into the desulfurization towerthrough the left water pump and the right water pump, so desulfurization reaction efficiency is improved, and time is saved; and through mutual cooperation of a rotary disc, a worm wheel, a worm, a cam, and arc-shaped block and other structures, the worm can be driven by the rotary disc to rotate, the worm drives the worm wheel to rotate, and the worm wheel drives the cam to rotate through the belt, so the cam drives the baffle to move through the arc-shaped block, and the device is more convenient and simpler to operate.