The invention relates to a method and a device for identifying a radionuclide Sr-89 and analyzing a nuclear purity. The method comprises the following steps of: (1), calibrating the activity of a sample and measuring the gamma radioactive source detection efficiency of a NaI gamma energy spectrometer; (3), calculating to obtain the emissivity of a gamma ray; (4), acquiring that the energy of the gamma ray is 909 Kev by the position of a gamma peak, obtaining that an energy specific value is approximately equal to 0.01% by the emissivity of the gamma ray and the activity of the sample, and determining that a nuclide is the Sr-89; and calculating to acquire the purity. The device comprises a lead chamber, a NaI crystal and photomultiplier, a lead tank, a plastic container, a penicillin bottle and a plastic cup. By using the method and the device, the strontium-89 nuclide and the nuclear purity are quickly and highly sensitively identified; by using the method and the device, the difficulty of a technical requirement on an operator is low; compared with the utilization of scintillating liquid, the amount of a radioactive waste can be reduced to improve the environment; meanwhile, the investment through which an enterprise needs to establish new equipment and an instrument is reduced; and the method and the device have a favorable application prospect.