The invention discloses a process for co-production of liquefied synthesis gas, pure
hydrogen and
methanol from
coke-oven gas. The process comprises the steps of: (a) firstly, purifying and compressing the
coke-oven gas, then enabling the gas after being subjected to the heat exchange of a heat exchange device to enter into a
methanol synthesis
tower for a
methanol synthesis catalytic reaction, exchanging heat of discharged gas by a
heat exchanger, and enabling the gas after being cooled by a cooler to enter into a methanol separator so as to obtain crude methanol; and (b) preparing refined methanol, enabling the gas to enter into a methanol washing
machine, washing away trace methanol in the gas with water, enabling partial gas after being compressed by a circular compressor to turn back to the
heat exchanger for methanol synthesis and enabling other gas to enter into a
heat exchanger for
methanation, enabling the gas to enter into a pre-heater after
heat energy is recycled, adding a small amount of aqueous vapor in the pre-heater and then enabling the gas to enter into a
methanation reaction furnace. According to the process disclosed by the invention, content of oxycarbide in the gas is reduced and the methanol product is obtained through resource recycling, residual small amount of oxycarbide is removed thoroughly and
hydrogen resource with high value is recycled, and the obtained
liquefied natural gas is convenient to transport.