The present invention relates to a method for manufacturing a nano-structured
metal oxide electrode, and in particular, to a method for manufacturing a
metal oxide electrode having a few tens or hundreds of nanometers in
diameter that is well adapted to an
electrode of a
supercapacitor using an
alumina or
polymer membrane having nano-sized pores as a template. Preferred methods for manufacturing a nano-structured
metal oxide electrode comprises steps of preparing an
alumina or
polymer template having a plurality of nano-sized pores;
sputtering a metal acting as a
current collector with a few tens of μm of thickness in one surface of the
alumina template; charging the template, after the
sputtering step, by submerging it into a
precipitation solution having a metal salt dissolved therein, and applying a static current or electrode
electric potential thereby electrochemically precipitating a metal oxide in the nano-sized pores of the template; a step in which the composite of the alumina or
polymer template and the metal oxide are contacted with a
sodium hydroxide solution or other base to remove the alumina or polymer template; and an optional
drying step to provide the nano-structured
metal oxide electrode.