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32results about How to "Excellent whitening resistance" patented technology

Method for synthesizing polyvinyl chloride modifier

ActiveCN101139425AHigh transparencyExcellent stress whitening resistancePolymer scienceEmulsion
The present invention relates to the synthesis method for a PVC resin anti-impact modifier butadiene, styrene, and methyl methacrylate copolymer. The preparation method is that a styrene butadiene polymerization emulsifier is firstly prepared. Then the solid content of electrolyte and latex in the emulsion is adjusted so as to generate styrene-butadiene rubber latex through polymerization reaction, the average particle diameter of which is from 80 to 280 nanometers. Then the prepared styrene-butadiene rubber latex experiences a three-step graft polymerization: the first step is styrene graft, the second ethyl acrylate graft and the last step methyl methacrylate graft. The cross-linking degree of the styrene-butadiene rubber latex is controlled in the styrene butadiene polymerization reaction so as to reduce stress blushing. In the third graft polymerization reaction, grafting agent is introduced in so as to enlarge the coverage of graft monomer on the rubber surface. MBS resin is finally obtained through agglomeration and drying treatment. The MBS resin obtained by the present invention is of good transparency, excellent stress blushing ability and anti-impact capability. The polymerization reaction system of the present invention is stable, which makes the content enhancement of the styrene-butadiene rubber latex possible.
Owner:BC P INC CHINA NAT PETROLEUM CORP +1

Waterborne polyurethane-acrylate hybrid resin and preparation method thereof, and application in leather finishing agent

The invention provides a waterborne polyurethane-acrylate hybrid resin and a preparation method thereof, and application in a leather finishing agent. The preparation method comprises the following steps: mixing and dissolving a diluted monomer and an isocyanate-terminated prepolymer, carrying out a neutralization reaction, carrying out high-speed shearing dispersion to obtain a pre-hybridized emulsion, and adding an initiator into the pre-hybridized emulsion to initiate polymerization, wherein the isocyanate-terminated prepolymer is obtained by mixing and reacting diisocyanate, macromolecularpolyol and a chain extender, and the macromolecular polyol comprises at least one of polyether diol and polyester diol. The waterborne polyurethane-acrylate hybrid resin prepared by the preparation method disclosed by the invention has the advantages that the preparation process is simple and controllable, and the leather finishing agent prepared from the waterborne polyurethane-acrylate hybrid resin is suitable for the field of high-end leather finishing agents, and has the advantages of high weather resistance, smooth hand feeling, good anti-sticking performance, good anti-whitening performance, good filler coating performance, high blackness and good scratch resistance.
Owner:WANHUA CHEM GRP CO LTD

Thick coating type whitening-resistant waterproof coating and preparation method thereof

The invention relates to a thick coating type whitening-resistant waterproof coating and a preparation method thereof. The coating comprises two components and comprises a component A and a component B, wherein the component A comprises the following substances in parts by mass: 30-60 parts of cement, 20-50 parts of filler, 10-40 parts of quartz sand, 0-10 parts of carbohydrates, 0-3 parts of a water reducing agent and 2-8 parts of calcium formate; and the component B comprises the following substances in parts by mass: 70-95 parts of a polymer styrene-acrylic emulsion, 2-8 parts of a polymer VAE emulsion, 0-1 part of a thickening agent, 1-7 parts of a defoaming agent, 0-4 parts of a bactericide and 50-200 parts of water. The waterproof coating disclosed by the invention is prepared by uniformly stirring and mixing the weighed substances of the component A and the component B according to the required proportion; when the double-component waterproof paint is applied in a thick-coating manner, the phenomenon that the surface of a coating is whitened is avoided, the double-component waterproof paint is high in adhesive force with a base layer, and the double-component waterproof paint has good physical and mechanical properties and an anti-whitening effect.
Owner:上海伟星新材料科技有限公司

A kind of water-based polyurethane-acrylate hybrid resin and its preparation method and application in leather finishing agent

The invention provides a water-based polyurethane-acrylate hybrid resin, a preparation method thereof, and an application in a leather finishing agent. The preparation method of the invention comprises: mixing and dissolving a diluting monomer and an isocyanate-terminated prepolymer, neutralizing After the reaction, high-speed shear dispersion is performed to obtain a pre-hybrid emulsion, and an initiator is added to the pre-hybrid emulsion to initiate polymerization; the isocyanate-terminated prepolymer is obtained by mixing and reacting diisocyanate, macromolecular polyol and chain extender. obtained; the macromolecular polyol includes at least one of polyether diol and polyester diol. The water-based polyurethane-acrylate hybrid resin prepared by the preparation method of the present invention not only has a simple and controllable preparation process, but also the leather finishing agent prepared from the above-mentioned water-based polyurethane-acrylate hybrid resin is suitable for the field of high-end leather finishing agents and has weather resistance It has the advantages of high performance, smooth hand feeling, good anti-sticking performance, good anti-blanking performance, good covering ability to fillers, high black transparency and good scratch resistance.
Owner:WANHUA CHEM GRP CO LTD
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