The invention discloses a novel flue gas desulfurization method, and belongs to the technical field of flue gas treatment. The novel flue gas desulfurization method comprises a desulfurization device,wherein the desulfurization device comprises a large annular pipe and a small annular pipe, the outer side wall of one end of the large annular pipe is communicated with a gas inlet pipe, the inner side wall of the other end of the large annular pipe is communicated with a gas guide pipe, the end, which is away from the large annular pipe, of the gas guide pipe is communicated with the small annular pipe, and the front outer wall of the end, which is away from the gas guide pipe, of the small annular pipe is communicated with a gas outlet pipe. A desulfurization ball mechanism is arranged incombination with dry desulfurization and wet desulfurization, desulfurization can be effectively and quickly carried out on the flue gas, and the desulfurization efficiency is high. With the arrangement of the large annular pipe and the small annular pipe, the flue gas flowing path can be prolonged, and the desulfurization effect can be improved. In addition, the structure is simple, and the occupied area is small. The drying ball mechanism is further arranged, the flue gas can be dried, the flue gas can be heated, and the flue gas is not subjected to significant cooling during the purification process.