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38results about How to "Suppress supercooling" patented technology

Silicon nitride-modified phase-change and energy-storage microcapsule and preparation method thereof

The invention discloses a silicon nitride-modified phase-change and energy-storage microcapsule, comprising a shell material and a cladded core material, wherein the shell material comprises the following raw materials in parts by weight: 50-100 parts of high-molecular polymers and 1-20 parts of silicon nitride powder which is evenly dispersed into the high-molecular polymers; the core material comprises 50-100 parts of organic phase-change and energy-storage materials and 1-20 parts of silicon nitride powder which is evenly dispersed into the organic phase-change and energy-storage materials. The invention also provides a preparation method of the phase-change energy-storage microcapsule. The thermal conductivity of the phase-change and energy-storage material is improved, overheat and overcold degrees in the phase-change process are inhibited, and meanwhile, the thermal endurance and the abrasive resistance, the thermal shock resistance, the fatigue resistance and the like also are improved. The silicon nitride-modified phase-change and energy-storage microcapsule is relatively simple in preparation technology, available in raw materials, strong in controllability, and applicable to the industrial large-scale production, an existing industrial processing technology can be fully utilized, and the performance of the phase-change and energy-storage microcapsule is improved.
Owner:SHENZHEN GRADUATE SCHOOL TSINGHUA UNIV

Supercooling phase change-inhibiting alkane microcapsule and preparation and application thereof

The invention discloses a supercooling phase change-inhibiting alkane microcapsule and preparation and application thereof. The size of the alkane microcapsule is within a range from 0.1Mu m to 100Mu m, the alkane microcapsule consists of shell materials and core materials, the shell materials are melamine resin, the core materials are n-alkane phase change agent and n-alkane nucleating agent, the carbon atom number of the n-alkane phase change agent is twelve to twenty eight, and the carbon atom number of the n-alkane nucleating agent is twenty two to forty. The preparation method for the alkane microcapsule, which is disclosed by the invention, is an in-situ polymerization method, and the preparation process includes core material emulsion preparation, shell material prepolymer preparation and alkane microcapsule preparation. For the same type of alkane microcapsule, the carbon atom number of the nucleating agent is greater than the carbon atom number of the phase change agent, and the nucleating agent and the phase change agent can be formed into gel. The invention has the advantages that: the alkane microcapsule has the characteristics of supercooling phase change inhibition, smooth surface and aggregation resistance, the preparation process for the alkane microcapsule is simple, and the application range is wide.
Owner:响水县中博纺织有限公司

Self-heating type reactor used for hydrogen production by reforming and filled with high-temperature phase-change material

The invention discloses a self-heating type reactor used for hydrogen production by reforming and filled with a high-temperature phase-change material. The self-heating type reactor used for hydrogen production by reforming is formed by sequentially laminating an upper cover plate provided with a methanol steam reforming reactant inlet pipe and a methanol catalytic combustion reactant inlet pipe on the upper surface, a graphite washer, an upper evaporation plate, a graphite washer, a lower evaporation plate, a graphite washer, a methanol reforming heat absorbing plate for hydrogen production filled with the high-temperature phase-change material on the lower surface, a sealing plate, a graphite washer, a methanol catalytic combustion plate filled with the high-temperature phase-change material on the lower surface, a graphite washer and a lower cover plate provided with a reformed gas outlet pipe and a combustion tail gas outlet pipe on the lower surface from top to bottom. The heat stability of a self-heating reactor is effectively improved by means of latent heat of phase change of the high-temperature phase-change material, the temperature gradient in the reactor and the temperature fluctuation of the reactor during working are reduced, catalyst activity reduction and peeling caused by overheating of the reactor are inhibited, and the heat efficiency and the methanol conversion rate of the reactor are improved.
Owner:ZHEJIANG UNIV

Low-carbon quasi-single crystal ingot furnace and method for adopting low-carbon quasi-single crystal ingot furnace for ingot casting

The invention discloses a low-carbon quasi-single crystal ingot furnace and a method for adopting the low-carbon quasi-single crystal ingot furnace for ingot casting. The low-carbon quasi-single crystal ingot furnace comprises a furnace body (1), a heat insulation cage (2) and a heat exchange table (9), wherein a crucible (7) is placed on the heat exchange table (9), the top of the crucible (7) is provided with heaters A (3), and heaters B (8) are distributed at the circumference of the crucible (7) and are connected with traction devices (12) through heater lifting rods (11). The method comprises five steps including material charging, heating melting, crystal growth, annealing and cooling. The low-carbon quasi-single crystal ingot furnace and the method have the advantages that the ingredient supercooling phenomenon caused by carbon content enriching in a solute boundary layer can be effectively inhibited, so the influence on the growth speed of quasi-single crystals caused by impurity enriching is reduced, and meanwhile, the content of carbon in quasi-single crystal ingots can be effectively reduced; and the generation and the growth of the fine crystal regions near the crucible wall can be effectively inhibited, so the quality of the quasi-single crystal ingots can be obviously improved, and the utilization rate of the ingots is improved.
Owner:TIANWEI NEW ENERGY HLDG +1

A kind of silicon nitride modified phase change energy storage microcapsule and preparation method thereof

The invention discloses a silicon nitride-modified phase-change and energy-storage microcapsule, comprising a shell material and a cladded core material, wherein the shell material comprises the following raw materials in parts by weight: 50-100 parts of high-molecular polymers and 1-20 parts of silicon nitride powder which is evenly dispersed into the high-molecular polymers; the core material comprises 50-100 parts of organic phase-change and energy-storage materials and 1-20 parts of silicon nitride powder which is evenly dispersed into the organic phase-change and energy-storage materials. The invention also provides a preparation method of the phase-change energy-storage microcapsule. The thermal conductivity of the phase-change and energy-storage material is improved, overheat and overcold degrees in the phase-change process are inhibited, and meanwhile, the thermal endurance and the abrasive resistance, the thermal shock resistance, the fatigue resistance and the like also are improved. The silicon nitride-modified phase-change and energy-storage microcapsule is relatively simple in preparation technology, available in raw materials, strong in controllability, and applicable to the industrial large-scale production, an existing industrial processing technology can be fully utilized, and the performance of the phase-change and energy-storage microcapsule is improved.
Owner:SHENZHEN GRADUATE SCHOOL TSINGHUA UNIV

A "core-shell" mesoporous silica/organic phase change material composite nanocapsule and its preparation method

The invention discloses a 'core-shell' type mesoporous silica / organic phase change material composite nano capsule and a preparation method thereof and belongs to the technical field of phase change energy storage materials. The nano capsule consists of a dense silica shell and a mesoporous silica / organic phase change material composite core, is of a long-range order mesoporous structure inside, has an external diameter smaller than 200nm, and is of a typical 'core-shell' structure; the organic phase change material accounts for 35-50wt% by mass of the nano capsule. The preparation method of the nano capsule comprises the following steps: implementing an emulsion template self-assembling method and an emulsion template interfacial polycondencation method, strictly controlling reaction conditions such as the amount of a surfactant, the core-shell raw material proportion and the stirring velocity, and carrying out in-situ formation in the sol-gel process, thereby obtaining the nano capsule. Compared with a conventional phase change microcapsule, the nano capsule disclosed by the invention has rapid thermal response and heat conduction velocities and low supercooling degrees, and high-sensitivity heat temperature adjustment and heat management can be effectively implemented.
Owner:BEIJING UNIV OF CHEM TECH

Supercooling phase change-inhibiting alkane microcapsule and preparation and application thereof

The invention discloses a supercooling phase change-inhibiting alkane microcapsule and preparation and application thereof. The size of the alkane microcapsule is within a range from 0.1Mu m to 100Mu m, the alkane microcapsule consists of shell materials and core materials, the shell materials are melamine resin, the core materials are n-alkane phase change agent and n-alkane nucleating agent, the carbon atom number of the n-alkane phase change agent is twelve to twenty eight, and the carbon atom number of the n-alkane nucleating agent is twenty two to forty. The preparation method for the alkane microcapsule, which is disclosed by the invention, is an in-situ polymerization method, and the preparation process includes core material emulsion preparation, shell material prepolymer preparation and alkane microcapsule preparation. For the same type of alkane microcapsule, the carbon atom number of the nucleating agent is greater than the carbon atom number of the phase change agent, and the nucleating agent and the phase change agent can be formed into gel. The invention has the advantages that: the alkane microcapsule has the characteristics of supercooling phase change inhibition, smooth surface and aggregation resistance, the preparation process for the alkane microcapsule is simple, and the application range is wide.
Owner:响水县中博纺织有限公司
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