40 results about "Acetone synthesis" patented technology

The invention relates to a method for producing methyl isobutyl ketone (MIBK) by using acetone (AC). An isopropyl alcohol (IPA) removing tower and a wastewater tower are added on the basis of the prior art; when the content of IPA in recovered AC is an arbitrary value in the range of 0.3 to 3 percent, the recovered AC is fed into the IPA removing tower to remove the IPA; when the content of the IPA in the recovered AC is less than 0.3 percent and is not increased any more, the recovered AC is directly fed into a reaction system; and part of oil phases of a phase separator on the top of an MIBK dehydrating tower and a product on the top of the wastewater tower are fed into the IPA removing tower to recover the AC and the MIBK. The aim can be fulfilled only by increasing less investment, the smooth operation of a production device is facilitated, the recovery rate of the AC and the yield of the MIBK are improved, and the consumption of the AC and energy is reduced, so that the production cost of the product is reduced, and the competitiveness of the product and the economic benefit of enterprises are improved.

The invention discloses a separating method of methyl isobutyl ketone synthesized by acetone, which is characterized by the following: increasing acetone extracting and recycling step based on four-tower flow path; recycling acetone in the 2-methyl pantane / acetone azeotropic material; reducing the consumption of acetone and manufacturing cost; improving product competitive power and economic benefit.

The invention discloses a process for preparing high-purity MIBK by utilizing industrial by-product waste liquid acetone. Including the reaction liquid that synthesizes MIBK from waste liquid acetone to obtain light components with a lower boiling point than acetone at the top of the light component removal tower, and obtain unreacted acetone at the top of the acetone recovery tower; obtain a boiling point lower than MIBK at the top of the process water tower / water azeotrope organic matter and MIBK / water azeotrope; low-boiling organic matter such as acetone and methanol from raw materials are obtained at the top of the dehydration tower; alcohol / water distillates are obtained at the top of the dealcoholization tower and A crude MIBK distillate is obtained; a light component with a boiling point lower than that of MIBK is obtained at the top of the MIBK refining tower and a MIBK product with a purity ≥ 99.5% is obtained from the side line. The technical process disclosed by the invention is simple, low in energy consumption, and low in production cost, and high-purity MIBK products can be obtained by using high-impurity waste liquid acetone, which has significant economic benefits.

The invention discloses a preparation method for a sulfuration palladium / alumina catalyst. The method comprises the following steps: preparing an acidic impregnating solution containing palladium and impregnating an alumina carrier in the impregnating solution containing palladium for a certain period of time; then adding a proper amount of a sodium alkyl xanthate solution drop by drop; and carrying out filtering, drying and roasting after completion of impregnation so as to obtain the sulfuration palladium / alumina catalyst. The method provided by the invention overcomes the disadvantage of mismatching between a hydrogenation function and a condensation dehydration function of conventional oxidized palladium / alumina catalysts for synthesis of methyl isobutyl ketone from acetone, and when used for synthesis of methyl isobutyl ketone from acetone, the prepared catalyst has superior reaction activity than catalysts used in conventional processes.

The invention relates to a catalyst, and belongs to the technical field of applications and development of acetone downstream products, wherein cobalt and tin are used as main active components, fluorine is used as an auxiliary agent component, aluminum oxide, silicon oxide or an aluminum oxide-silicon oxide composite carrier with rich pH value is selected to promote a reaction, the catalyst is used under a mild reaction condition, an one-step acetone synthesis process is used, the yield of methyl isobutyl ketone in the application of the catalyst of the present invention is higher than the yield of methyl isobutyl ketone in the application of the palladium / resin catalyst used in the current industrial apparatus, and a large amount of isopropanol are by-produced. According to the present invention, the obtained catalyst has the ideal stability, has the cost significantly lower than the cost of the existing palladium catalyst, and has good economic benefits.

The invention discloses a preparation method of a sulfuration mode Pd / Al2O3 catalyst. The method comprises the following steps: 1, preparing a sodium alkyl xanthate solution and a palladium-containing dipping liquid which is acidic; 2, dipping an alumina carrier in the palladium-containing dipping liquid, filtering, drying, spraying parts of the palladium-containing dipping liquid, and drying to obtain a catalyst intermediate; and 3, adding the catalyst intermediate to the remaining palladium-containing dipping liquid, dipping, drying, and roasting to obtain the sulfuration mode Pd / Al2O3 catalyst. A volume ratio of the palladium-containing dipping liquid used for spraying to the palladium-containing dipping liquid used for dipping is 1.0:1.0-1.0:3.0, and preferably 1.0:1.5-1.0:2.5. The catalyst obtained through the method realizes higher activity, higher selectivity and longer life than present catalysts prepared through present methods in the synthesis process of methyl isobutyl ketone from acetone.

The invention relates to a catalyst for synthesizing methyl isobutyl alcohol and isopropanol from acetone, a preparation method and application thereof, in the field of catalysts. The catalyst for synthesizing methyl isobutyl alcohol and isopropanol from acetone includes the following components in parts by weight as a whole: a, 0.5 to 8 parts of at least one from copper or copper oxides; b, 0.5 parts ~10 parts from at least one of cobalt or cobalt oxide; c, 82 to 99 parts of carrier; said carrier is selected from at least one of silicon oxide, aluminum oxide and zirconium oxide modified by high-temperature roasting titanium. In the present invention, the active components copper and cobalt are loaded on the titanium-modified carrier through the ammonia distillation method, the distribution of the metal active component is relatively more uniform, the interaction between the metal active component and the carrier is enhanced, and the activity and stability of the catalyst are improved. And the catalyzer of the present invention adopts the non-precious metal component copper and cobalt of low composition, and cost is low; Not only can produce methyl isobutyl alcohol, also can co-produce isopropanol, industrial production device is stronger to the adaptability of market, enterprise Increased profitability.

The invention discloses a catalyst for synthesis of 2,6-dimethyl-4-heptanone from acetone and a preparation method for the catalyst. The catalyst comprises an active ingredient Ni and a carrier ZrO12-MnO2; based on the total weight of the catalyst, the content of the active ingredient Ni is 1 to 10 weight percent, preferably 3 to 6 weight percent, the content of MnO2 is 1 to 20 weight percent, preferably 5 to 10 weight percent, and the balance is ZrO2. The catalyst disclosed by the invention is applied to a reaction for synthesis of the 2,6-dimethyl-4-heptanone from the acetone, and has the characteristics that conversion rate of the acetone serving as a raw material is high; the selectivity of the 2,6-dimethyl-4-heptanone serving as a product is high, that is the yield of the 2,6-dimethyl-4-heptanone serving as a target product is high.

The invention relates to a catalyst for synthesizing methyl isobutyl ketone and diisobutyl ketone from acetone, a preparation method and application thereof in the field of catalysts. The catalyst for synthesizing methyl isobutyl ketone and diisobutyl ketone from acetone is measured as 100 parts by the overall weight of the catalyst, and includes the following components: a, 0.5 to 10 parts of at least One; b, 0.5-10 parts of at least one selected from cobalt or cobalt oxides; c, 80-99 parts selected from bismuth-modified basic calcium phosphate. The preparation process of the catalyst of the present invention is relatively simple, easy to control, and the active components should not be lost; the catalyst of the present invention can not only produce methyl isobutyl ketone, but also diisobutyl ketone, and the industrial production device has better adaptability to the market. Strong, the cost of the bimetallic catalyst of the present invention is significantly lower than that of the existing palladium catalyst, and has better economic benefits.

The invention discloses a silver-ruthenium bimetal doped graphene catalyst and its preparation method and application. The catalyst includes a graphene carrier, and the graphene carrier is loaded with silver and ruthenium nanoparticles, and the mass ratio of silver and ruthenium nanoparticles is 0.5 ~1: 0.6~1.1, the diameter of silver and ruthenium nanoparticles is 100~800nm. The preparation method of this catalyst comprises the following steps: (1) prepare graphene; (2) make AgBF 4 with RuCl 3 Dissolving in ethylene glycol, adding graphene, and reacting under hydrothermal conditions; (3) cooling, centrifuging, washing, and vacuum drying to obtain the product; (4) roasting. The catalyst is used as a catalyst in the synthesis process of bisphenol F or 1-phenyl-3-p-nitrophenyl-acetone. When the catalyst is used in the synthesis of bisphenol F, it has excellent catalytic performance, significantly improves the yield of bisphenol F, and the side reaction products are effectively reduced; when used in the synthesis of 1-phenyl-3-p-nitrophenyl-acetone It has excellent catalytic performance, the product chemical selectivity is 100%, the yield is greater than 90%, and it can be recycled and reused.