28 results about "Persistent luminescence" patented technology

A long-persistent luminescence emitter containing a polymer that contains, relative to the total molar amount of an electron donor structural unit and an electron acceptor structural unit therein, 70 mol % or more of an electron donor structural unit and less than 30 mol % of an electron acceptor structural unit, or containing a polymer that contains, relative to the total molar amount of an electron donor structural unit and an electron acceptor structural unit therein. 70 mol % or more of an electron acceptor structural unit and less than 30 mol % of an electron donor structural unit. The emission decay after stopping light irradiation to the emitter is power law decay.

The invention discloses a Tb < 3 + > activated niobate green stress luminescent material, and relates to the technical field of luminescent materials. The expression general formula of the mechanical luminescent material is (Ca2-xSrx) Nb2O7: yTb, x is greater than or equal to 0 and less than or equal to 1, and y is greater than 0 and less than or equal to 0.09; a high-temperature solid-phase method is adopted, and the preparation process comprises the following steps: 1) burdening; 2) grinding and drying; 3) sintering; and 4) grinding. The stress luminescent material provided by the invention has unique green stress luminescence after being radiated at 254 nm for 3 minutes, the spectral range of niobate stress luminescence is successfully expanded to a green area, the key problem that the existing niobate stress luminescent material has single luminescence color is solved, and the application potential of the material is remarkably improved; and the material shows excellent continuous luminescence performance, can continuously emit light for more than 5 minutes after an excitation light source is turned off, and has very wide application value in the fields of visual stress sensing, anti-counterfeiting encryption and the like.

The invention relates to the technical field of biosensing, and discloses a pH / viscosity double-lock activated afterglow luminescent small molecule probe as well as a preparation method and application thereof. The structural formula of the afterglow luminescent small-molecule probe is shown in the specification. A rhodamine light-emitting unit and an afterglow light-emitting matrix unit SO are covalently connected through a chemical bond. The luminescent mechanism is as follows: under illumination, molecules generate singlet oxygen to oxidize and activate adjacent SO units, so that active oxygen mediated afterglow luminescence is generated. The afterglow luminescent small-molecule probe has a double-lock activation characteristic, that is, a strong afterglow signal can be generated only when a subacid environment and a high-viscosity condition are met at the same time. And the signal is weak under a single condition or a normal physiological environment. The probe provided by the invention has excellent environmental specificity and high signal-to-noise ratio imaging capability, and provides a powerful tool for realizing accurate imaging in a complex biological system.

The invention discloses a tumor targeted nano photodynamic therapy system and a preparation method thereof. The preparation method comprises the following steps: preparing porous NaYF4: Er-coated NaGdF4 persistent luminescent nanoparticles; the preparation method comprises the following steps: preparing ES-PEG-p (API-PPA)-Ce6; eS-PEG-p (API-PPA)-Ce6 and a hydrophilic drug are mixed, NaYF4: Er-coated NaGdF4 is dropped, encapsulation of PLNPs and formation of micelles are induced, polyether F-127 is added, the pH value is adjusted to be neutral, and the tumor targeting nanometer photodynamic therapy system is prepared. The tumor targeting nanometer photodynamic therapy system has reversible'on-off 'afterglow characteristics, combines accurate surgical navigation with enhanced ROS generation, can be used in combination with PDT, is used for targeted therapy of deep tumors such as pancreatic cancer, and has high clinical application value.

An optical material comprising a fluoride with a formula MF 2, wherein M is selected from the group of Ca, Sr, Ba, doped with rare earth ions, showing a persistent luminescence after stimulation with a femtosecond source.

The invention discloses a preparation method and application of an all-weather photocatalyst. The all-weather photocatalyst is a covalent heterojunction composite photocatalytic material prepared by vertically growing ZnIn2S4 on the surface of Sr2MgSi2O7: Eu < 2 + >, Dy < 3 + >. The mass ratio of the ZnIn2S4 to the Sr2MgSi2O7 to the Eu < 2 + > to the Dy < 3 + > is (0.5-1): 1. The long-afterglow luminescent material (Sr2MgSi2O7: Eu < 2 + >, Dy < 3 + >) is prepared by adopting a recrystallization melting method, and compared with a traditional melting calcination method and a sol-gel method, the long-afterglow luminescent material has the advantages of good afterglow performance, low calcination temperature and short preparation time; through an interface covalent bond connection strategy, ZnIn2S4, Sr2MgSi2O7: Eu < 2 + > and Dy < 3 + > construct a compact heterojunction composite system, the structure stability is good, spatial separation of photon-generated carriers is promoted, the problem of photocatalytic all-weather degradation of organic pollutants is solved by utilizing the continuous luminescence characteristic of a long-afterglow material and the catalytic activity continuously maintained under a dark condition, and the material has good application prospects. The photocatalyst prepared by the invention also has the beneficial effect of resisting escherichia coli.

The invention provides an outdoor grating anti-interference system, which comprises at least one path of infrared emission device used for emitting an infrared coding optical signal representing the unique identity of the infrared emission device; the infrared coding light signal is a pulse sequence emitted in an instantaneous high driving current state within the single maximum continuous light emitting duration, the pulse sequence is composed of a plurality of discrete light emitting pulses with the same width, and the sum of the widths of the light emitting pulses is equal to the single maximum continuous light emitting duration; the at least two paths of infrared receiving devices are used for receiving the infrared coding optical signals from the same infrared transmitting device at the same time; the coding processing unit is connected with the infrared receiving devices and is used for decoding the infrared coding optical signals received by each path of infrared receiving devices; only when all infrared receiving devices corresponding to the same light path cannot correctly decode the identity label from the infrared coding light signal of the light path, it is judged that the light path is shielded. The shielding misjudgment can be reduced, and the anti-interference capability of the outdoor grating is improved.

The invention provides a 1, 2-dioxetane derivative as well as a preparation method and application thereof, and belongs to the technical field of chemiluminescent substrates. The 1, 2-dioxetane derivative provided by the invention has high luminous efficiency and good stability. The result of the embodiment shows that the time required by the 1, 2-dioxetane derivative provided by the invention to reach the maximum luminescence peak value at 25 DEG C is only 5-30 minutes, and the continuous luminescence time can reach 70 minutes.

An aircraft includes fuselage walls, a passenger cabin between the fuselage walls, rows of seating arranged with an aisle through the rows, an emergency exit in the fuselage walls, an access path between the rows of seating to the emergency exit from the aisle, and a marker forming tracks on a floor of the aisle and access path, to direct passengers to the emergency exit. The marker includes a photoluminescent material exhibiting persistent luminescence and comprising a pigment that emits blue visible light in response to excitation by light of wavelength between 250-500 nm. The photoluminescent material has an emission spectrum providing light which appears blue to a viewer, with a maximum peak intensity between 400-510 nm. The marker includes a cover over a top surface of the photoluminescent material that partially blocks light of some UV range wavelengths whilst being transparent to other wavelengths in the UV range.

The invention relates to the technical field of sports goods, and particularly discloses a high-brightness day and night double-effect fluorescent badminton string and a preparation method thereof. The badminton string adopts a three-layer composite structure of a core wire layer, a composite fluorescent functional layer and a high-light-transmittance protective wear-resistant layer, and the core wire layer is formed by twisting polyester fibers or ultra-high molecular weight polyethylene fibers and provides basic mechanical support; the composite fluorescent functional layer adopts a daytime fluorescent pigment-long-acting light-storing fluorescent powder compound system, and is matched with nano reflective beads to enhance the light reflection efficiency, the composite fluorescent functional layer continuously emits light for more than or equal to 12 hours in a dark environment after being irradiated by a light source for 10-20 minutes, and the visible distance under natural light in daytime is more than or equal to 8 meters; the high-light-transmittance protective wear-resistant layer is made of modified polyamide resin with the light transmittance larger than or equal to 85%, and the tensile strength of spherical lines is larger than or equal to 30 MPa while the light emitting effect is guaranteed. The technical defects that an existing fluorescent badminton string is insufficient in luminous intensity at night and poor in visual effect in the daytime are overcome, and the day and night use requirements can be met without additional power supply equipment.

The invention relates to escape route markings (1), especially for public transport vehicles, such as commercial aircraft. The escape route marking (1) comprises a lighting element (3) which luminesces in the dark and whose emitted light exits at an outer face (2) of the escape route marking (1), wherein the lighting element (3) comprises a granular material immobilized by a carrier material (20) and composed of at least translucent particles (10), wherein the average size of the granular-material particles (10) is greater at least by a factor of 10 than the average grain size of the sustained-luminescence pigments (11) contained therein.

The application provides a preparation method of a phosphorescent biosensor for specifically detecting messenger RNA. In the application, a phosphorescent biosensor is constructed by using phosphorescence resonance energy transfer (PRET) between polydopamine (PDA) and persistent luminescence nanoparticles (PL). The biosensor comprises a PDA particle carrier and three nucleic acid chains, one of which is a hairpin chain (H) that is complementary to target TK1 mRNA, one is a DNA chain (PL-DNA) that is combined with the persistent luminescence nanoparticles through an amide bond, and the other is a substrate chain (S-15A) that is complementary to the PL-DNA. In the absence of the target, the phosphorescence of the PL is absorbed by the PDA, resulting in a weak signal; after the target is added, the target opens the H, and the exposed flexible end displaces the PL-DNA from the S-15A, so that the PL is away from the PDA, the PRET is closed, the phosphorescence signal is restored, and the phosphorescence signal is enhanced with the increase of the concentration of the target, and the linear relationship is 0-200 nM. The detection limit of the application is 1.74 nM.

The invention discloses an organic long-lasting luminescent material with a narrow-band emission characteristic and application thereof, and belongs to the field of organic long-lasting luminescent materials. The donor comprises one or more of the following materials; the receptor includes:.

The application relates to a preparation method and application of a metal-organic framework (MOFs) material with photochromic and long persistent luminescence (LPL) characteristics. Specifically, X-MOFs (X=Cl, Br) are prepared by high-temperature self-assembly of ligand 1,1'- (6-hydroxy-1,3,5-triazine-2,4-diyl) bis (pyridine-4 (1H)-ketone) and CdCl2.2.5H2O and CdBr2. Research finds that, under the continuous irradiation of ultraviolet light, the X-MOFs realize photochromic behavior from yellow to gray. In addition, after the removal of different excitation light sources, the X-MOFs exhibit multicolor LPL which is dependent on excitation, temperature and time evolution. The X-MOFs material synthesized by the application provides potential application value in the fields of data encryption and anti-fake patterns.

The utility model discloses a power supply device and electronic equipment, and relates to the technical field of circuits, the power supply device comprises a light emitting circuit and a control circuit connected with the light emitting circuit, and the light emitting circuit comprises a photoreceptor and a light emitting module; the photoreceptor is arranged in a sensing range corresponding to the light-emitting module; and the photoreceptor is connected with the control circuit. Compared with the prior art, the control circuit can obtain the light-emitting condition of the light-emitting module in real time through the photoreceptor, the control circuit can accurately judge whether the light-emitting module has the abnormal light-emitting condition or not according to the light-emitting condition, that is, the light-emitting module still emits light continuously under the condition that the control circuit controls the power supply device not to provide electric energy; furthermore, the control circuit can judge that the internal relay is adhered, so that the light-emitting module still continuously emits light under the condition that the power supply device does not provide electric energy, the control circuit can accurately judge whether the internal relay is adhered or not, and the judgment complexity and cost are low.

The invention discloses a silicon nanodot, a high-performance super-long continuous light-emitting silicon nanodot composite material, a preparation method of the composite material and an application of the composite material in information encryption, and develops an economical, simple, convenient and innovative strategy, the silicon nanodot is integrated into a composite matrix, and the composite material is prepared. And the high photoluminescence quantum yield of the SiNDs is effectively combined with the stability of a substrate to triplet excitons. The phosphorescence quantum yield (PhQY) of the obtained material is up to 81.04%, the afterglow life is as long as 3.44 seconds, meanwhile, macroscopic cyan emission is accompanied, the duration time is up to 52 seconds, and the material is one of reported long-afterglow luminescent systems with the best performance. The high-performance multicolor long afterglow material is obtained with lower manufacturing cost and a simpler technological process, the problems that an existing afterglow material is low in phosphorescence quantum yield, single in function, potential in pollution and the like are effectively solved, and a new solution is provided for the field of information encryption and the like.

A class of metal halide-based metal-organic frameworks (MOFs) materials with multicolor tunable long-lasting emission and white light properties were synthesized by self-assembly of 15-crown ether-5 (CE) ligands and metal halide salts (CdX2), resulting in three complexes (15-5-CdCl2, 15-5-CdBr2, and 15-5-CdI2). In the solid state, the complexes (15-5-CdCl2, 15-5-CdBr2, and 15-5-CdI2) all exhibited near-standard white light emission under 340 nm ultraviolet radiation at room temperature, with CIE coordinates of (0.28, 0.32), (0.31, 0.39), and (0.30, 0.34), respectively. Simultaneously, they exhibit excitation-dependent room-temperature phosphorescence (RTP) ranging from blue / cyan to green / yellow, with 15-5-CdCl2 and 15-5-CdBr2 exhibiting multicolor tunable and visible light luminescence (LPL) with time-resolved luminescence lifetimes as high as 1-2 seconds. Single-crystal X-ray diffraction analysis and theoretical calculations indicate that the bright LPL of 15-5-CdCl2 and 15-5-CdBr2 originates from the aggregation state induced by the 15-crown ether-5 ligand and halogen bonds. The LPL obtained in this way can be widely used in lighting and display devices, optical recording devices, biological imaging, security systems, and other fields.

The present invention relates to a ceramic or glass-ceramic material corresponding to one of the following formulas: [(Sr1-a1-b1 Xa1X'b1)1-e REe]12+c [(Al1-dYd)1-fMf]20+2c[(Si1-gZg)1-hMh]12-2cO66 formula (I) [(Sr12-a2-b2 Xa2X'b2)1-e REe][(Al1-dYd)1-fMf]20[(Si1-gZg)1-hMh]12O66 formula (II) in which: X represents at least one alkaline earth metal excluding barium, X' represents at least one alkaline earth metal, RE represents at least one element selected from the group consisting of rare earths, bismuth (Bi) and one of their combinations, Y represents at least one element selected from the group consisting of metalloids, of poor metals, non-metals and one of their combinations, M represents at least one transition metal, Z represents at least one element chosen from the group consisting of metalloids, non-metals and one of their combinations, 0 ≤ a1 ≤ 10 ≤ b1 ≤ 1 / 30 ≤ a2 ≤ 120 ≤ b2 < 120 ≤ c < 10 ≤ d < 1 e, f,g and h are greater than or equal to zero and strictly less than 1. Figure for the abstract: no figure.

Aspects of the disclosure relates to articles, compositions, and systems for targeted cargo delivery and release. In some embodiments, the disclosure relates to metal organic frameworks (MOF). The MOFs comprise a plurality of metal clusters and a plurality of ligands that are coordinated with the plurality of metal clusters. In some embodiments, the disclosure relates to the MOFs possessing azobenzene moiety sensitive to hypoxic conditions. In some embodiments, the disclosure relates to one-dimensional coordination polymers being utilized for drug delivery for cancer treatment. While in some embodiments, the disclosure relates to the persistent luminescent phosphors and their photoluminescence behaviour in the presence of oxygen. Lastly, in some embodiments, the disclosure relates to how MOFs have been employed in OLED technology because of their tunable nature, large surface area and their versatile chemistry. Thus, MOFs play an important role in photovoltaic technology and expanding the market for sustainable energy solutions.

The invention relates to an AI-based night lamp energy-saving control method and device, and the method comprises the following steps: monitoring a night lamp coverage area through employing an infrared human body sensor, generating a human body existence signal, dynamically dividing the area according to the human body existence signal, and forming an activity thermodynamic diagram; and in combination with the light intensity data, the brightness demand value of each region is calculated by using an AI analysis model, and then a dimming instruction is sent to the partitioned light source module of the night lamp. The instructions are converted into electric signals through the PWM driving controller, regional brightness output of the LED light source array is adjusted, and the energy-saving lighting effect is achieved. The process effectively meets the brightness requirements of different areas, and meanwhile the purpose of saving energy is achieved. The technical problems that a traditional night lamp mostly adopts a normally-on or simple human body induction switch mode, the illumination intensity and range cannot be dynamically adjusted according to an actual use scene, and consequently, the night lamp still continuously emits light in an unmanned or low-activity area, and electric energy is wasted are solved.

The invention provides an ultrahigh-temperature long-lasting luminescent material and a preparation method thereof. The ultrahigh-temperature long-lasting luminescent material is a compound composed of a boron oxide crystalline lens and polycyclic aromatic hydrocarbon molecules, the polycyclic aromatic hydrocarbon molecules are uniformly dispersed and embedded in the boron oxide crystalline lens in a single molecule form, and the boron oxide crystalline lens is a semitransparent crystalline lens generated by in-situ dehydration of boric acid molecules. The ultrahigh-temperature long-lasting luminescent material disclosed by the invention has an extremely high luminescent temperature which is up to 400 DEG C. The luminescent color of the ultra-high-temperature long-lasting luminescent material can be adjusted from purple to dark red, the luminescent wavelength (386-780 nm) covers the range from ultraviolet to near infrared, and the ultra-high-temperature long-lasting luminescent material has the characteristic of time and temperature dependence; the average service life of the ultra-high-temperature long-lasting luminescent material can reach 2138ms in a room-temperature air environment, the afterglow time which can be distinguished by naked eyes can reach 24s in the room-temperature air environment, and the ultra-high-temperature long-lasting luminescent material is stable in long-lasting luminescent performance and can be stored for a long time.

The present invention relates to a ceramic or glass-ceramic material corresponding to one of the following formulae: [(Sr1-a1-b1 Xa1X'b1)1-eREe] 12+c[(Al1-dYd)1-f Mf] 20+2c [(Si1-gZg)1-hMh]12-2cO66 formula (I) [(Sr12-a2-b2Xa2X'b2)1-eREe][(Al1-dYd)1-fMf]20[(Si1-gZg)1-hMh]12O66 formula (II) wherein: - X represents at least one alkaline-earth metal with the exception of barium; - X' represents at least one alkaline-earth metal; - RE represents at least one element selected from the group consisting of rare earths, bismuth (Bi), and one of the combinations thereof; - Y represents at least one element selected from the group consisting of metalloids, post-transition metals, non-metals, and one of the combinations thereof; - M represents at least one transition metal; - Z represents at least one element selected from the group consisting of metalloids, non-metals and one of the combinations thereof; - 0 ≤ a1 ≤ 1 - 0 ≤ b1 ≤ 1 / 3 - 0 ≤ a2 ≤ 12 - 0 ≤ b2 < 12 - 0 ≤ c < 1 - 0 ≤ d < 1 - e, f, g and h are greater than or equal to zero and strictly less than 1.

The invention discloses a sunshade curtain assembly, a glass assembly and a vehicle. The sunshade curtain assembly comprises first curtain cloth, second curtain cloth and a light-emitting component. The second curtain cloth and the first curtain cloth are arranged in a stacked mode. The light-emitting component is fixed between the first curtain cloth and the second curtain cloth, and emergent light provided by the light-emitting component is emitted into the vehicle through the second curtain cloth. The light-emitting delay structure is arranged on an emergent path of the emergent light. By the adoption of the sunshade curtain assembly, the light-emitting delay structure can emit light after being excited by the emergent light provided by the light-emitting component, the light-emitting delay structure can still continuously emit light for a period of time after the light-emitting component stops working, the light-emitting time of the sunshade curtain assembly is prolonged, and therefore under the condition that the total light-emitting time is determined, the light-emitting time of the sunshade curtain assembly is prolonged. The working time of the light-emitting component can be shortened, the service life of the light-emitting component is prolonged, the light-emitting delay structure can avoid sudden change of light rays, gentle light and shadow transition is created, and the use scene requirements of extreme environments such as high temperature and high humidity are met.

The present application relates to the technical field of microfluidics, and particularly relates to a microfluidic chip based on real-time droplet tracking, which is provided with a TFT array in a lower substrate, and the OLED pixels and the light-emitting elements or the photoelectric detection elements in the OPD array are powered, and the droplet movement in the microfluidic channel is controlled through the driving electrode array arranged on the lower substrate; in operation, the light-emitting elements continuously emit light, the photoelectric detection elements continuously detect the light signals, the light emitted by the light-emitting elements is reflected by the droplet and then detected by the photoelectric detection elements, so as to change the light signals detected by the photoelectric detection elements, thereby the droplet position can be accurately tracked. It can be understood that the microfluidic chip has a simple overall structure, and the real-time feedback of the droplet position can be realized through the microfluidic chip itself, without the need of additional detection equipment, so that the cost is low and the operation is convenient.

The invention belongs to the technical field of long-lasting luminescent materials (OLPL), and particularly relates to a TMB (Tetramethylbenzidine) derivative for constructing a high-performance organic long-lasting luminescent material. The invention discloses preparation of N, N, N ', N'-tetramethyl benzidine (TMB) derivatives for constructing high-performance organic long-lasting luminescence (OLPL) materials, and the OLPL materials are composed of luminescent molecules, electron donors and organic matrixes or composed of electron donors and organic matrixes. Structural modification and preparation of various TMB derivatives are realized through two-step reaction of Suzuki-Miyaura coupling and Buchwald-Hartwisting coupling, the conditions are mild, and the method is simple. The three-component or double-component OLPL material is obtained by doping through a melting method. Compared with a classical electron donor TMB, the OLPL material obtained based on the TMB derivative has excellent afterglow brightness and lasting time under the conditions of air environment and room temperature, the OLPL strength can be improved by 1-2 orders of magnitude, and the afterglow lasting time is greatly prolonged and can reach more than 3 hours.

The invention discloses a preparation method of homogeneous up-conversion self-excitation infrared light-emitting particles. The light-emitting particles comprise microcrystal particles with calcium sulfide as a core matrix material and up-conversion light-emitting nanoparticles with calcium sulfide as a matrix material, the homogeneous calcium sulfide microcrystal particles and nano-particles form up-conversion self-excited infrared light-emitting particles with core-shell structures through a potassium silicate solution; after drying, a fluidized bed chemical vapor deposition technology is used, and the surfaces of the up-conversion self-excitation infrared light-emitting particles are coated with aluminum oxide moisture-proof layers, so that the up-conversion self-excitation infrared light-emitting particles have good moisture resistance; near-infrared light is used for irradiating the nano-particles, and the continuously luminous up-conversion nano-particles excite the microcrystal particles to emit light at the same time, so that the luminescence attenuation of the microcrystal particles which excite luminescence is made up, and the continuous luminescence and sensitivity of the infrared luminous particles are improved.

The present application relates to the technical field of light emitting, in particular to a kind of singlet fission sensitization type photochemical long afterglow system and application based on.The photochemical long afterglow system of the present application includes at least one sensitizer, at least one buffer and at least one luminophore;Wherein, the sensitizer has singlet fission property, and the absorption peak of the sensitizer and the emission peak of the luminophore peak position zero overlap.Due to the unique performance of the sensitizer singlet fission, singlet oxygen production efficiency is as high as 140%, directly breaks through the upper limit of the level of traditional photosensitizer.At the same time, the absorption of photosensitizer molecule and the emission of rare earth complex zero overlap, improve the upper limit of the optimal application concentration of photosensitizer.The integration of the two factors significantly enhances the light energy absorption conversion capacity of the system, directly realizes high-performance rare earth photochemical long afterglow luminescence in organic solution phase.

The invention relates to the technical field of crystalline functional materials, in particular to a metal-organic bromide material with a multicolor adjustable long afterglow characteristic as well as a preparation method and application of the metal-organic bromide material. The chemical formula of the material is [ZnBr2 (byb)] n, byb is 1, 3-bis (benzimidazole-1-yl methyl) benzene, and the preparation method comprises the following steps: under a solvothermal condition, adding a mixed solvent of zinc oxide, 1, 3-bis (benzimidazole-1-yl methyl) benzene, N, N '-dimethylformamide, water and HBr into a reaction kettle, and carrying out heating reaction, cooling, washing and drying. According to the material prepared by the invention, fluorescence emitted by the material is continuously adjustable from purple to cyan to yellow under excitation of ultraviolet light with different wavelengths, and after an excitation source is removed, the material emits bright long-lasting light which can last for several seconds and is widely adjustable from green to yellow to orange; excitation dependent type long-life phosphorescence emission from green to orange is displayed, and it is indicated that the material has huge application potential in the fields of encryption, anti-counterfeiting, information storage and the like.