The invention discloses a device for spraying carbon to deoxidize by using a slag stopping system. The device comprises an injection tank, a specially-made slag stopping cone vehicle and a specially-made slag stopping cone, a fluidistor is installed on the lower portion of the injection tank, powder is driven by main blowing gas after being fluidized and passes through a pipeline in the middle ofa large arm of the slag stopping cone vehicle and a rotary joint at the tail end of the pipeline, finally, the powder enters molten steel through an injection pipeline in the center of the specially-made slag stopping cone, a powder conveying pipeline in the middle of a large arm of the slag stooping cone is in close fit with the injection pipe in the center of the slag stopping cone through the rotary joint, and positioning is carried out on a slag stopping cone vehicle clamping head by clamping an outer pipe of a slag stopping cone rod, so that positioning of the slag stopping cone in the injection process is guaranteed. According to the method, online powder spraying deoxidation in the steelmaking and tapping process is realized, the initial oxygen content of the molten steel before reaching a steel ladle is reduced, the usage amount of deoxidized alloy and the generation of deoxidized inclusions are reduced, the yield of high-value alloy is increased, and a good foundation is laidfor improving the product quality.