The present invention is directed to bioconjugates of complexes represented by the formula:wherein R, R′, R1, R′1, R2, R′2, R3, R′3, R4, R′4, R5, R′5, R6, R′6, R7, R′7, R8, R′8, R9, R′9, M, X, Y, Z and n are defined herein for use as contrast agents in diagnostic imaging.