The invention discloses a high-quality harmless utilizing method of a 
hyperaccumulator. The high-quality harmless utilizing method comprises the following steps: smashing and 
drying the 
hyperaccumulator, and sieving through a 
sieve of which the density is 100 meshes; carbonizing at a 
carbonization temperature being 450 to 550 DEG C and in 
carbonization time being 25 to 35 minutes, thus obtaining acarbonized material; immersing the carbonized material by using an alkaline solution of which the 
mass percentage is 45 to 55 percent; 
drying at 90 to 120 DEG C for 10 to 15 hours after immersing for20 to 28 hours, thus obtaining an amorphous particulate carbon block; activating the amorphous particulate carbon block into an 
activated carbon coarse product under a 
nitrogen atmosphere, wherein the activating temperature is 750 to 850 DEG C, and the activation time is 25 to 35 minutes; 
drying for 10 to 15 hours, thus obtaining 
metal-containing 
activated carbon with a 
catalytic effect; grindingthe 
activated carbon, thus obtaining an activated product HA-AC; adding 5 to 15 percent of the activated 
carbon product HA-AC to 
biomass or other reaction raw materials; putting a swelled material ina supercritical reaction kettle, and carrying out sealing reaction at the 
reaction temperature being 380 to 600 DEG C and the reaction pressure being 22.1 to 30 MPa, thus obtaining a 
hydrogen-rich gas. The high-quality harmless utilizing method disclosed by the invention has the advantages that additional 
metal loading is not required, a complicated preparation technology and a longer preparationperiod are not required, heavy 
metal can be fully stabilized, and secondary 
pollution can be avoided.