40results about How to "Promote decarbonization" patented technology

The invention relates to low-silicon high-carbon chromium bearing steel. The low-silicon high-carbon chromium bearing steel is prepared from the following chemical components in percentage by mass: 0.80-1.10% of C, 0.01-0.15% of Si, 0.20-0.60% of Mn, 1.20-1.60% of Cr, 0.15-0.50% of Mo, less than or equal to 0.05% of Al, less than or equal to 0.025% of P, less than or equal to 0.020% of S, less than or equal to 0.001% of Ca, less than or equal to 0.003% of Ti, less than or equal to 0.0008% of O, less than or equal to 0.04% of As, less than or equal to 0.03% of Sn, less than or equal to 0.005% of Sb, less than or equal to 0.002% of Pb and the balance of Fe and unavoidable impurities. A production flow comprises the following steps: electric furnace or converter smelting; external refining; VD or RH vacuum degassing; continuous casting; continuous rolling; shearing; stack cooling; finishing; flaw detection; and packaging. A low silicon technology is adopted based on existing high-carbon chromium bearing steel GCr15, and the chemical components are re-designed, so that not only are the demands on strength, hardness, toughness, wear resistance, hardenability and the like of a steel product met, but also the overheating sensitivity and decarburizing and cracking tendency of the steel product are improved.

The invention discloses a liquid combustion-supporting sulfur-fixing coal additive and a using method of the additive; the liquid combustion-supporting sulfur-fixing coal additive comprises the following components in percentage by weight: 3-7.5% of KMnO4, 3-8% of Cu(NO3)2, 2-7.5% of Fe(NO3)3, 8-18% of Ca(NO3)2, 3.5-6% of Al(NO3)3, 8-18% of KNO3, 0.5-2.5% of NaVO3, and the balance of H2O. The liquid combustion-supporting sulfur-fixing coal additive provided by the invention uses water as a solvent and each component is at an ionic state, has relatively high reaction activity at a high temperature and has high combustion efficiency and an excellent sulfur fixing effect, and the sulfur fixing efficiency is more than 40%.

The invention discloses an Al-Mg-C brick for a steel ladle lining. The Al-Mg-C brick is prepared from 50%-70% by weight of Al-Mg-C reclaimed materials, 5%-20% by weight of magnesia, 10%-25% by weightof alpha-Al2O3, 3%-10% by weight of AlN, 2%-6% by weight of crystalline flake graphite, 2%-3% by weight of SiC and 2.5%-3.5% by weight of phenolic resin. Due to addition of AlN, compared with a traditional Al-Mg-C brick, the Al-Mg-C brick is more resistant to high-temperature scouring, expansion coefficient of a brick body is reduced at the use temperature, volume stability is maintained, AlN is not corroded by molten metal, and slag resistance of the material is improved; a small amount of graphite is added, so that molten steel decarburization is facilitated, and the type of ultra-low carbonsteel is smelted; a large quantity of the Al-Mg-C reclaimed materials are adopted, therefore, the use quantity of high-bauxite clinkers or corundum particles is greatly reduced, the production cost is lower, and the Al-Mg-C brick has better social benefits and economic benefits.

The invention discloses a combustion-supporting coal additive and an application method thereof. The coal additive comprises the following components in percentage by weight: 3-7.5% of KMnO4, 3-8% of Cu(NO3)2, 2-7.5% of Fe(NO3)3, 1.5-6% of Zn(NO3)2, 6-14% of KNO3, 5-10% of NaNO3, 0.5-1.5% of NaVO3 and the balance of H2O. The combustion-supporting coal additive disclosed by the invention uses water as a solvent, and the components are in an ionic state, so the combustion-supporting coal additive has high reaction activity; the combination of the components in the additive can promote the decarburization and cracking reactions of the coal as well as the sufficient combustion of volatile compounds and fixed carbon, enhance the combustion efficiency of the coal, and save the coal by 4-10%.

The invention relates to the technical field of the steelmaking industry, in particular to a method for steelmaking and denitrification of a VD furnace through CO2. The method for steelmaking and denitrification of the VD furnace through CO2 is suitable for the VD refinement of 30-350 t of steel ladles. According to the refinement process, bottom blowing of CO2 or CO2-Ar is performed through the steel ladles; different bottom blowing modes are adopted in all stages, the small-flow gas mixing bottom blowing is adopted in the liquid steel composition even-mixing stage, and liquid steel oxidationis prevented and the vacuumizing speed is increased; the high-flow bottom blowing of pure CO2 is adopted in the high vacuum decarburization stage, decarburization of CO2 is promoted, and then deep denitrification is achieved and dehydrogenation is enhanced; normal operation of a bottom blowing component is ensured by switching bottom blowing of Ar and high-pressure spraying and blowing in the bottom blowing repetition stage; and in the liquid steel purifying stage, bottom soft blowing of CO2-Ar mixed gas is performed, rapid flotation of nonmetal inclusions is promoted, and at the same time, CO2 gas is the main part of blowing, heat impact on a bottom blowing nozzle is reduced, the bottom blowing service life is prolonged, and finally low-cost smelting of low-nitrogen steel through the VDfurnace is achieved.

The invention discloses a liquid combustion-supporting sulfur-fixing coal additive and a using method of the additive; the liquid combustion-supporting sulfur-fixing coal additive comprises the following components in percentage by weight: 3-7.5% of KMnO4, 3-8% of Cu(NO3)2, 2-7.5% of Fe(NO3)3, 8-18% of Ca(NO3)2, 3.5-6% of Al(NO3)3, 8-18% of KNO3, 0.5-2.5% of NaVO3, and the balance of H2O. The liquid combustion-supporting sulfur-fixing coal additive provided by the invention uses water as a solvent and each component is at an ionic state, has relatively high reaction activity at a high temperature and has high combustion efficiency and an excellent sulfur fixing effect, and the sulfur fixing efficiency is more than 40%.

The invention discloses a method for pre-degrading organic high-concentration oil refining organic wastewater by synergism of sulfuric acid free radical and anodic oxidation. The method comprising the following steps: building an electrolytic cell by taking a Ti / SnO2-Sb-Pt oxide electrode as an anode; adding wastewater to be degraded and SO4<2->; switching on a power supply for electrolysis; while the wastewater is degraded, generating HSO5<-> and S2O8<2-> in a system; sampling and measuring the concentration of S2O8<2-> every 10 minutes; when the concentration of S2O8<2-> reaches a certain degree, filling the wastewater into a reaction tank; and adding catalysts Fe<2+> and Co<2+> to catalyze the generation of the sulfuric acid free radical so as to further degrade the wastewater. With the method, the sulfuric acid free radical and the anodic oxidation are organically combined, and a sulfate radical serves as an auxiliary electrolyte, HSO5<-> and S2O8<2-> can be automatically generated in the system while the wastewater is oxidized and degraded in an anodic area; and then the catalysts are added to catalyze the generation of the sulfuric acid free radical, thereby degrading organic matters in oil refining wastewater, which are difficult to degrade, and improving the biological property of the wastewater.

The invention aims to provide a method for improving the liquid metal corrosion resistance of martensitic heat-resistant steel. The method is characterized by: firstly pre-plating a titanium layer on the surface of martensitic heat-resistant steel, then making the carbon on the surface layer of the martensitic heat-resistant steel react with the pre-plated titanium layer on the surface by means of vacuum heat treatment, thus finally forming a ceramic coating of titanium carbide. By employing the method to treat the surface of martensitic heat-resistant steel, the liquid metal corrosion resistance of metal can be effectively improved, and the service life of metal materials can be prolonged.

The invention relates to low-silicon high-carbon chromium bearing steel. The low-silicon high-carbon chromium bearing steel is prepared from the following chemical components in percentage by mass: 0.80-1.10% of C, 0.01-0.15% of Si, 0.20-0.60% of Mn, 1.20-1.60% of Cr, 0.15-0.50% of Mo, less than or equal to 0.05% of Al, less than or equal to 0.025% of P, less than or equal to 0.020% of S, less than or equal to 0.001% of Ca, less than or equal to 0.003% of Ti, less than or equal to 0.0008% of O, less than or equal to 0.04% of As, less than or equal to 0.03% of Sn, less than or equal to 0.005% of Sb, less than or equal to 0.002% of Pb and the balance of Fe and unavoidable impurities. A production flow comprises the following steps: electric furnace or converter smelting; external refining; VD or RH vacuum degassing; continuous casting; continuous rolling; shearing; stack cooling; finishing; flaw detection; and packaging. A low silicon technology is adopted based on existing high-carbon chromium bearing steel GCr15, and the chemical components are re-designed, so that not only are the demands on strength, hardness, toughness, wear resistance, hardenability and the like of a steel product met, but also the overheating sensitivity and decarburizing and cracking tendency of the steel product are improved.

The invention discloses a composite steel-making technology with a function of improving steel-making precision, relates to the technical field of steel-making and solves the problems of unstable molten steel composition and low precision. The method comprises the steps of converter steel-making and LF (ladle furnace) steel-making. With adoption of an oxygen supply mode based on constant lance position and variable pressure, slag making and slag melting are facilitated, dynamic conditions of reaction in the furnace are greatly improved, and decarburization, dephosphorization and desulfurization are promoted, besides, ultrasonic waves are introduced during adding of a first slag-making material, fast reaction of the slag-making material and molten steel is promoted, and precision of the molten steel composition is improved; by means of introduction of the ultrasonic waves, argon flow can be reduced during addition of the slag-making material, consumption of argon is reduced, and steel-making cost is reduced; the ultrasonic waves are introduced during adding of the slag-making material, so that the slag-making material is dispersed uniformly and prevented from caking, and the impurities in the slag-making material are prevented from remaining in the molten steel.

The invention discloses an impurity removal process and device for a scintillation rotary-floating calcining furnace. The process comprises the following steps that materials calcined in the scintillation rotary-floating calcining furnace enter a high-temperature cyclone separator from an outlet of the scintillation rotary-floating calcining furnace to be subjected to gas-solid separation; gas separated by the high-temperature cyclone separator enters a preheating system; and materials separated by the high-temperature cyclone separator are conveyed to fluidization impurity removal equipment through a discharge valve. The method has the technical effects that impurities in the product can be more effectively removed, the purity of the product is improved, and the economic benefit is increased.

The invention discloses a converter steelmaking process, and relates to the technical field of steelmaking in order to solve the problem of metal loss during constant-pressure variable gun position oxygen supply. The converter steelmaking process comprises the following steps that firstly, molten iron and scrap steel are prepared, the molten iron is added into a converter, and then the preheated scrap steel is added into the converter; secondly, a gun is lowered to blow oxygen inwards, a first batch of slagging materials are added at the same time, and during oxygen blowing, a constant gun position variable pressure oxygen supply mode is adopted; thirdly, a second batch of slagging materials are added after five to six minutes for continuous converting; fourthly, converter turning down, temperature measurement and sampling are conducted, and the reblowing time is determined; and fifthly, the gun is lifted up, steel is discharged, and low-nitrogen carbon powder, alumcakes, silicomanganese, ferrosilicon and lime are sequentially added, and secondary refining outside the converter is conducted. The converter steelmaking process is beneficial to slag formation and slug melting, avoidssplashing, reduces metal loss, and promotes decarburization, dephosphorization and desulfuration.

The invention discloses an RH vacuum refining furnace and a vacuum refining system, and belongs to the technical field of secondary steelmaking of molten steel. The vacuum refining system comprises the RH vacuum refining furnace, a steel ladle base, a first air supply device, a second air supply device, a vacuum pump and an alloy hopper. The RH vacuum refining furnace comprises a vacuum chamber and a dip pipe. The dip pipe comprises a center pipe and an outer sleeve. The outer sleeve is an inverted cone frustum-shaped hollow pipe. The area of the upper bottom face of the outer sleeve is larger than that of the lower bottom face of the outer sleeve. The top of the center pipe is fixedly connected with the outer sleeve through a fixing beam, and the center pipe and the outer sleeve are located on the same axis. The center pipe is an ascending pipe and is also an inverted cone frustum-shaped hollow pipe. The area of the upper bottom face of the center pipe is larger than that of the lower bottom face of the center pipe. An annular sleeve formed by the center pipe and the outer sleeve is a descending pipe. According to the RH vacuum refining furnace and the vacuum refining system, the saturation point of gas flow in molten steel of the vacuum refining system is increased, circular flow is also increased, distribution of gas in a molten steel flow field is improved, and thus the refining effect of the molten steel is improved.

A method to promote RH decarburization. Before or during the decarburization of ultra-low carbon steel RH, aluminum or aluminum alloy is added to the molten steel, and the aluminum-oxygen reaction is used to form dispersed Al in the molten steel. 2 o 3 Inclusions, generated Al 2 o 3 The inclusions have poor wettability and large wetting angle with molten steel, and become the heterogeneous nucleation core of carbon monoxide bubbles generated by RH decarburization reaction, which promotes the nucleation of carbon monoxide bubbles, increases the nucleation depth of carbon monoxide bubbles in molten steel, and expands The thickness of the reaction layer for the carbon-oxygen reaction in the RH vacuum tank improves the deep decarburization ability of the RH. The method can effectively increase the RH decarburization rate, and the carbon content at the end point is reduced by 1 to 10×10 ‑6 . The generated carbon monoxide bubbles are small in size and have a strong ability to capture inclusions, which can promote the formation of Al in advance. 2 o 3 Inclusions are removed without polluting molten steel.

The invention discloses a system and a method for treating the high-concentration landfill leachate in an aerobic composting site. The system comprises a hydraulic screen, a regulation pool, an anoxic and anaerobic pool, an upflow anaerobic pool, an anoxic pool, a first aerobic pool, a second aerobic pool, a secondary sedimentation pools, an immobilized microorganism aerating biological filtering pool, an MBR (membrane biological reaction) pool, a nanofiltration system, a decolourising pool and a charcoal canister which are connected in sequence. The raw landfill leachate is treated by the hydraulic screen, the regulation pool, the anoxic and anaerobic pool, the upflow anaerobic pool, the anoxic pool, the first aerobic pool, the second aerobic pool, the secondary sedimentation pools, the immobilized microorganism aerating biological filtering pool, the MBR pool, the nanofiltration system, the decolourising pool and the charcoal canister of the system in sequence so that the effluent can be recovered. The effluent can meet the requirement for the limit of the discharge concentration of the water pollutant in the special region in the Domestic Waste Landfill Site Pollution Control Standard GB16889-2008.

The invention relates to the technical field of converter smelting, in particular to a smelting method of a top-bottom combined blowing converter. The method comprises the steps of during a process of utilizing the top-bottom combined blowing converter for blowing molten steel, and when the oxygen supply rate of the top-bottom combined blowing converter is 80 to 85 percent, adding limestone in the molten steel; during a process of utilizing an oxygen lance for blowing oxygen to the molten steel added with the limestone, converting a the lance position of the oxygen lance according to a preset lance position conversion frequency and a preset lance position conversion sequence. According to the smelting method of the top-bottom combined blowing converter provided by the invention, when the oxygen supply rate of the top-bottom combined blowing converter is 80 to 85 percent, the limestone is added in the molten steel and is decomposed in the molten steel, the generated carbon monoxide and carbon dioxide can further play a role in stirring, and the sufficient balance between melting slags and furnace steel slags is promoted, so that carbon-oxygen equilibrium of a converter terminal can be further reduced.

The invention relates to a method for smelting steel with high phosphorus content, which is suitable for a 180-250 ton converter, comprising: adjusting the position of the oxygen lance and the intensity of the oxygen supply according to the amount of oxygen supplied during the blowing process of the converter; End point control; the end point control includes: in terms of mass percentage, MgO is controlled at 15-18%; FeO is controlled at 9-12%; end-point phosphorus is controlled at 0.030%-0.070%; the basicity R of the slag at the end of the converter is controlled at 2.0% -2.5. The smelting method can increase the phosphorus content at the end point of the converter and reduce the consumption of the phosphorus-iron alloy, and is suitable for smelting steel types with a finished product phosphorus content ≥ 0.070% in terms of mass percentage.

The invention discloses a powder decarburization system. The powder decarburization system comprises a decarburization furnace, a feed hopper, a rotating and lifting actuator, material-collecting hoppers, a combustor, material distributors, a high temperature dust remover and a main blast pipe, wherein the feed hopper is arranged on the top of the decarburization furnace; the top of the decarburization furnace is provided with a flue gas outlet, the bottom is provided with a gas-solid heat exchanger; the inside of the decarburization furnace is provided with the material-collecting hoppers, air-distributing pipes are evenly arranged on the inner wall; the combustor is arranged between the lowest material-collecting hopper and the gas-solid heat exchanger; the air outlet of the gas-solid heat exchanger is communicated with the main blast pipe, the air-distributing pipes are communicated with the main blast pipe; the material distributors are arranged below the outlets of the feed hopper and the material-collecting hoppers; and the material distributors are driven by the rotating and lifting actuator. The powder decarburization system adopts powder decarburization, mineral aggregatemoves down through the material-collecting hoppers, the heat generated through decarburization is utilized to preheat the mineral aggregate, the gas-solid heat exchanger is used to preheat air, the waste heat of the high temperature mineral aggregate is used to preheat air, the combusted flue gas is circulated to the inside of the furnace through the back part of the high temperature dust removerso as to adjust the temperature; and instant decarburization is realized in the decarburization furnace and the decarburization temperature is accurately controlled.

The invention provides an industrial flue gas synchronous decarburization and denitrification and waste heat recycling device, the device comprises a decarburization and denitrification tower, ammonia spraying equipment and reaction bed layers, the decarburization and denitrification tower is provided with a flue gas inlet and a flue gas outlet, the decarburization and denitrification tower is internally provided with a plurality of reaction bed layers, and the ammonia spraying equipment is provided with ammonia spraying equipment; the plurality of reaction bed layers are located between the flue gas inlet and the flue gas outlet, a heat exchange inlet and a first heat exchange outlet are formed in the side wall of the decarburization and denitrification tower, an ammonia water inlet is formed in the side wall of the decarburization and denitrification tower, the ammonia spraying equipment is arranged in the decarburization and denitrification tower, and the ammonia water outlet is formed in the side wall of the decarburization and denitrification tower. And the ammonia water inlet is communicated with the ammonia spraying equipment. According to the technical scheme, the arrangement in the decarburization and denitration tower can be dynamically adjusted according to the temperature of the flue gas, decarburization and denitration are carried out in the decarburization and denitration tower at the same time, the equipment investment of step-by-step treatment can be greatly saved, the occupied area can be reduced, and the cost and the operation cost are saved.