An electrochromic structure with self-powered operation comprises: a photoelectric element having a first glass substrate, a
solar power generation structure, and a second glass substrate; a reflective
film structure having a glass substrate, an auxiliary layer, and a
reflective layer, wherein the reflective
film structure is bonded to the photoelectric element with a first resin; and an electrochromic element having a first transparent conductive glass layer, a first electrochromic layer, an
electrolyte layer, a second electrochromic layer, and a second transparent conductive glass layer, wherein the electrochromic element is disposed on the reflective
film structure and stacked with a second resin to form the electrochromic structure, and the electrochromic element is electrically connected to the photoelectric element. Therefore, the electrochromic structure can be self-powered, improves power generation efficiency, reduces the use of substrate glass, and lowers production costs.