This application provides a method for selectively separating
vanadium and
chromium from
chromium-
vanadium slag leachate, relating to the field of
solid waste recycling. The method includes: diluting a hydrophobic eutectic
solvent with a
diluent to obtain an extractant; mixing the extractant with the
chromium-
vanadium slag leachate, performing shake extraction, allowing the mixture to stand and separate phases to obtain a vanadium-loaded organic phase and a
raffinate; washing and back-extracting the organic phase to obtain a vanadium-poor organic phase and a vanadium-rich back-extract; then subjecting the vanadium-rich back-extract to vanadium
precipitation treatment and a first
calcination to obtain vanadium
pentoxide; the hydrophobic eutectic
solvent is obtained by heating and stirring a mixture of a
hydrogen bond donor and a
hydrogen bond
acceptor, wherein the
hydrogen bond
acceptor is composed of a neutral
phosphorus-containing
organic compound and a hydrophobic
quaternary ammonium salt. This method can achieve selective separation of vanadium and chromium, effectively solving the problem of vanadium and chromium separation from chromium-vanadium
slag leachate, and has good application prospects in the field of selective separation of vanadium and chromium to prepare high-purity vanadium and chromium products.