The present application relates to a kind of methods for separating
vanadium and
arsenic,
phosphorus,
silicon from
vanadium-containing solution.The
separation method of the present application comprises the following steps: (1) after the
vanadium-containing solution is cooled and crystallized, adjust pH and add
crystallization promoter, after stirring reaction,
solid-liquid separation is obtained, and mixed salt and vanadium-containing
impurity removal liquid is obtained;
Vanadium-containing
impurity removal liquid is added to concentrated
sulfuric acid to adjust pH, after heat preservation reaction,
solid-liquid separation is obtained, and dihydrogen tetrasodium decavanadate and acid
precipitation mother liquor are obtained; (2) dihydrogen tetrasodium decavanadate is dissolved in water,
sodium hydroxide is added to adjust pH, and
ammonium salt is added, and after
solid-liquid separation and washing,
ammonium metavanadate is obtained;
Vanadium-containing solution is
sodium metavanadate solution, and the impurities in
sodium metavanadate solution include
phosphorus element,
arsenic element and
silicon element.The process of the present application is simple, the
reaction conditions are mild, high-purity
ammonium metavanadate is prepared, vanadium and
phosphorus,
arsenic,
silicon and other
impurity elements are deeply separated,
sodium sulfate is recycled, the investment of equipment is low, the economic benefit is good, the environment is friendly, and it is suitable for industrial large-scale application.