35 results about "Oxygen diffusion coefficient" patented technology

A semiconductor device has: a silicon substrate; a silicon oxide layer formed on the surface of the silicon substrate; a high dielectric constant insulating film including a first oxide layer formed above the silicon oxide layer and made of a high dielectric constant film having a dielectric constant higher than silicon oxide and a first nitride layer formed above the first oxide layer and made of nitride having an oxygen intercepting capability, or a high dielectric constant insulating film including a first oxide film formed on the silicon oxide layer, a second oxide layer formed on the first oxide layer and a third oxide layer formed on the second oxide layer, the first and third oxide layers having an oxygen diffusion coefficient smaller than the second oxide layer; and a gate electrode formed on the high dielectric constant insulating layer and made of oxidizable material.

The invention relates to a composite coating and application thereof in a carbon/carbon composite material, and belongs to the technical field of manufacturing of an anti-oxidizing carbon/carbon composite material. An SiC coating which is similar to a coefficient of thermal expansion of the carbon/carbon composite material is adopted as a base transition layer; the SiC coating is prepared by adopting an in situ chemical reaction method; gradient transition of Si-C is achieved on carbon/carbon composite material matrix; the binding strength of the carbon/carbon matrix and the SiC coating is enhanced; the difference of thermal expansion between the carbon/carbon matrix and an M-Si-O coating is effectively relieved; the M-Si-O coating with high temperature resistance grade, low oxygen diffusion coefficient and high thermal emissivity is selected as an outer coating; the M-Si-O coating is prepared by sol dipping-high temperature sintering treatment.

A wavelength converting element (101, 102, 103, 110) comprising a polymeric carrier material comprising a first wavelength converting material adapted to convert light of a first wavelength to light of a second wavelength, wherein the oxygen diffusion coefficient (D) of the polymeric carrier material is 8×10⁻¹³ cm²/s or less at 25° C. A prolonged lifetime of the wavelength converting material is achieved by selecting a polymeric carrier material with an oxygen diffusion coefficient (D) at 8×10⁻¹³ cm²/s or less at 25° C.

The invention relates to a refractory metal high-temperature antioxidant Si-Mo-YSZ coating and a preparation method thereof. The refractory metal high-temperature antioxidant Si-Mo-YSZ coating is madefrom, by weight, 45-65% of Si, 25-40% of Mo, 2-15% of YSZ (yttria-stabilized zirconia), and 2-8% of additives. Materials of coating are made into a slurry first; the slurry is applied to the surfaceof a refractory metal; the refractory metal is sintered at 1370-1530 DEG C for 20-90 min. since the coating composition is reasonably made in conjunction with thermal expansion coefficient of a refractory metal base, the coating, during use, can quickly form a ZrSiO4-ZrO2-SiO2 composite oxide film, effectively reducing oxygen diffusion coefficient of the coating, and implementing long-term antioxidant use of various refractory metals at the temperature of 1700 DEG C and above. The preparation method is simple and low in cost; the coating has good thermal matching with a base; high-temperatureoxidation resistance of refractory metals can be effectively improved.

The invention discloses a device and method for measuring the diffusion coefficient of dissolved oxygen in a biological membrane. The device comprises a gas delivery device, an intake gas humidification bottle, a biological membrane measuring chamber and a dissolved oxygen microelectrode system. The method for measuring the diffusion coefficient of the dissolved oxygen by utilizing the device comprises the following steps: placing a to-be-measured biological membrane sample into the biological membrane measuring chamber, and introducing nitrogen to reduce the concentration of oxygen in the system to be the minimum; then changing intake gas into oxygen, and meanwhile using a dissolved oxygen microelectrode to record the curve about time-dependent change of the dissolved oxygen in the biological membrane; repeating the test in different positions and different depths of the biological membrane, so as to obtain multiple pieces of sample data; simulating the process through a mathematical model and fitting model data and data measured in the test, and calculating the diffusion coefficient of the dissolved oxygen. According to the invention, the time consumed is short, and precise chemical analysis is not required, so that the measuring result is accurate, the repeatability is good, and the system error is very small.

The invention discloses a sliding type device for measuring the oxygen exchange coefficient and the oxygen diffusion coefficient. The sliding type device comprises an experimental platform device, a material conductivity test device, an input and output device, a data analysis system, a gas mixing device, an atmosphere pre-heating device and a gas detecting device, wherein a to-be-measured experimental material sample arranged on a sample table is switched in different experimental cavity atmospheres in the whole testing process, a gap between a sliding shaft and each shaft hole in the cavity wall is reduced through thermal expansion at the high temperature by the aid of a sealing part machined precisely, and accordingly, sealing between cavities is realized; a gas mixing device is used for providing different oxygen partial pressure test gases; an atmosphere pre-heating device is used for controlling the gas temperature; the data analysis system is used for performing signal data fitting computation to obtain the oxygen exchange coefficient and the oxygen diffusion coefficient. According to the sliding type device for measuring the oxygen exchange coefficient and the oxygen diffusion coefficient, signal data are collected by the test device, so that data of the oxygen exchange coefficient and the oxygen diffusion coefficient of the material are obtained accurately and rapidly, and the material performance data are obtained.

The invention provides a nanometer multilayer coating, a preparation method of the nanometer multilayer coating and a cutter with the surface coated with the nanometer multilayer coating, and belongsto the technical field of protective coatings. The nanometer multilayer coating provided by the invention comprises (AlCrTiZrMo)N nanometer layers and Cr2O3 nanometer layers which are sequentially andalternately laminated on the surface of a substrate. According to the nanometer multilayer coating provided by the invention, a coherent boundary is formed between the (AlCrTiZrMo)N nanometer layersand the Cr2O3 nanometer layers, then dislocation movement is hindered, and the hardness of the nanometer multilayer coating is high; and due to the fact that modulation layers are the Cr2O3 nanometerlayers with low oxygen diffusion coefficient, the thermal stability of the nanometer multilayer coating is better than that of the (AlCrTiZrMo)N single-layer coating. The nanometer multilayer coatingprovided by the invention has both high hardness and high thermal stability, the defects in the use of a traditional tool coating can be made up, the research range of the tool coating is widened, andthe performance requirements of high-speed cutting and dry cutting are satisfied.

The invention discloses a method for determining an oxygen diffusion coefficient in a cement-based material. The method comprises the following steps of (1) preparation of a to-be-tested specimen of a cement-based material; (2) connection of a test device; and (3) determination of the oxygen diffusion coefficient Df in the cement-based material. The invention further provides a test device for determining the oxygen diffusion coefficient in the cement-based material. The test device comprises an air supply system, a specimen, left and right gas chambers and a sensing test system. The driving force of oxygen diffusion in the whole process is only concentration gradient, so that the diffusion coefficient of the oxygen in the specimen of the cement-based material can be determined, the measurement method is simple and data are accurate and reliable. A data foundation can be provided for further research of the corrosion process of the oxygen on steel rebar in the cement-based material through determining the transmission rule of the oxygen in the cement-based material.

The invention discloses a method for calculating an oxygen diffusion coefficient of polydimethylsiloxane. The method comprises the following specific steps: establishing a hydrogen-containing siliconeoil cross-linking agent and vinyl-terminated PDMS molecular structure model and then carrying out geometric optimization; marking the reaction atoms; constructing a molecular model and performing geometric optimization to obtain unit cells; according to the mechanism of the cross-linking reaction, realizing automatic cross-linking of reaction chemical bonds in the hydrogen-containing silicone oilcross-linking agent and the vinyl-terminated PDMS prepolymer through a Perl script program; after a cross-linking model is obtained, newly building oxygen molecules, and building unit cells of an oxygen-containing molecular model and a cross-linking molecular model; carrying out NPT dynamic calculation on the optimized unit cell; obtaining the mean square displacement of the oxygen in the unit cell; and obtaining the diffusion coefficient of the oxygen in the cross-linked molecules through an Einstein equation. According to the method, the crosslinking process of the reaction can be analyzedfrom the molecular perspective, and the process conditions for improving the oxygen diffusion coefficient in the PDMS film preparation process are further obtained.

The invention belongs to the field of solid oxide fuel cells, in particular relates to a solid oxide fuel cell structure and a preparation method thereof. The cell structure comprises a cell cathode layer, an electrolyte layer and a cell anode layer in sequence from top to bottom, wherein the cell cathode layer is divided into a PrBaCo2O5 layer and an LSM (La0.8S0.2MnO3) layer from top to bottom; the electrolyte layer is YSZ (Yttria Stabilized Zirconia); the cell anode layer is Ni-YSZ; and the thickness of the PrBaCo2O5 layer is 2-4 microns. Because PrBaCo2O5 has higher catalytic performance, oxygen diffusion coefficients, surface exchange coefficients and oxygen ion migration capability, the oxygen adsorbing capability and oxygen dissociating capability of a cathode can be improved by adopting a PrBaCo2O5-LSM/YSZ/Ni-YSZ structure and material system; and the solid oxide fuel cell structure has the characteristic of improving the cathode performance of the solid oxide fuel cells.

The invention provides a thin film deposition preparation method and a preparation method of a nano-fiber structure flexible buffer layer, and belongs to the technical field of materials. The thin film deposition preparation method comprises a temperature rise step and a deposition step. The thin film deposition preparation method is characterized in that in the deposition step, an included angle between the normal line of a deposition source and the normal line of the surface of a substrate ranges from 30 to 80 degrees. The preparation method provided by the invention has the advantages that a heat stress release mechanism with excellent performance is provided, and a nano-fiber structure Al2O3 flexible buffer layer thin film prepared by the preparation method has excellent flexibility and insulation property and low oxygen diffusion coefficient.

The invention provides a preparation method of a molybdenum disilicide series oxygen diffusion coefficient verifying diaphragm, and method used for calculating film oxygen diffusion coefficient. The preparation method comprises following steps: SiO2 base solution preparation, oxidation corrosion resistant doped solution preparation, mixing of a working mother liquor B into a working mother liquor A at different ratios, silicon chip washing, silicon chip doping film preparation, and baking of generated amorphous film in a high temperature tubular furnace. The preparation method is capable of prolonging the service life of MoSi2 heating elements, increasing using temperature, and realizing accurate verifying of oxygen diffusion coefficient, so that the industrial value is high, and the application prospect is promising; and at the same time, the method used for calculating film oxygen diffusion coefficient is simple, convenient, and accurate, and possesses significant meaning in study on high temperature corrosion mechanisms.

The invention relates to the field of concrete oxygen diffusion coefficient determination devices, in particular to a device for measuring the oxygen diffusion coefficients in concrete with differentsaturations under the action of continuous tension and compression. The device comprises a to-be-tested piece, an oxygen diffusion device and a continuous tension and compression load device, whereinthe oxygen diffusion device is formed by connecting a central circle gas diffusion chamber and an outer circle gas diffusion chamber in a concentric circle structure, and the oxygen diffusion device is tightly attached to the to-be-tested piece through a rubber pad to form a closed space, and the continuous tension and compression load device is arranged in the vertical direction of the gas diffusion surface, so that the oxygen diffusion coefficient at any position of the test piece can be detected, and the detected oxygen diffusion coefficient is the oxygen diffusion coefficient under the continuous load and is closer to the actual engineering operation.

The invention discloses a method for measuring soil relative gas diffusion coefficients under different soil water potentials and volume weights, and belongs to the technical field of soil water potential and relative gas diffusion coefficient measurement. The method comprises the following steps: respectively measuring water potentials corresponding to soil cores with different preset volume weights by using a specific soil water potential measuring device, and respectively measuring oxygen diffusion coefficients corresponding to the soil cores with different preset volume weights by using a specific soil relative gas diffusion coefficient measuring device; and thus, the soil water potential and the soil relative gas diffusion coefficient value corresponding to each soil core with the preset volume weight are obtained. According to the method, the field soil water potential and the soil relative gas diffusion coefficient corresponding to different soil bulk density states can be simulated under the indoor condition, the soil air permeability can be measured, and emission of greenhouse gas N2O and the like can be predicted.