The invention belongs to the field of metallurgy casting and smelting, and particularly discloses a thermal shock resistant ceramic tube mold and a preparation method thereof. The thermal shock resistant ceramic tube mold comprises an inner ceramic tube mold, wherein an outer steel-made tube mold layer sleeves the outer side of the inner ceramic tube mold; a self-flowing thermal-resistant casting material is filled between the inner ceramic tube mold and the inner ceramic tube mold; the inner ceramic tube mold is made of the following raw materials in percentage by weight: 40-50% of carbon silicon micro powder, 20-25% of silicon powder, 20-25% of primary aluminum nitride powder, 2-5% of graphite micro powder, 2-3% of zirconium oxide micro powder, 0.5-1% of yttrium oxide micro powder, 0.2-0.5% of absolute ethyl alcohol and 3-4% of an adhesive. The thermal shock resistant ceramic tube mold is high in pressure resistance, good in breaking strength, good in high temperature corrosion resistance and long in service life; when nodular cast iron tubes are produced by using the thermal shock resistant ceramic tube mold, the production procedures can be reduced, the energy is saved, the equipment maintenance expense is reduced, and the production cost is lowered, so that the nodular cast iron pipe thermal shock resistant ceramic tube mold has great significance for the metallurgy tube industry and has wide application prospect and popularization values.