The invention discloses an inorganic silicon-aluminum dry-powder paint for an exterior wall. The paint is composed of powder and water and is characterized in that a weight ratio of the powder to water is 1: 0.2 to 1: 0.6; and the powder comprises, by weight, natural resin, a sal material, a fibrous material, quartz powder, sand, sulfonated hyperbranched polypyrrolone-modified graphene oxide, polybenzimidazole-modified meso-porous silicon, KH-560 and inorganic pigment. The inorganic silicon-aluminum dry-powder paint is eco-environment friendly, does not contain volatile harmful substances like VOCs, formaldehyde and ammonia, has ultra-long service life which is identical to the service life of the wall, and has excellent weatherability, acid and alkali resistance, anti-powdering performance, color retention performance, temperature and humidity adjustment performance and ecological functionality, and good construction operability.