The invention discloses a purification method of a decorative base paper titanium dioxide production material, and belongs to the technical field of sulfuric acid method titanium dioxide production. The method is performed in a crystallizing tank with a stirrer, and comprises the following steps: A, feeding titanium sulfate solution into the crystallizing tank, and starting the stirrer; B, controlling pressure in the crystallizing tank to cool down a material; C, leading auxiliary steam into the crystallizing tank, meanwhile leading auxiliary circulation water into the crystallizing tank, andcontrolling tank feeding temperature and tank discharging temperature of the auxiliary circulation water, pressure in the tank and material temperature in the tank; D, leading main steam into the crystallizing tank, meanwhile leading main circulation water into the crystallizing tank, and controlling tank feeding temperature and tank discharging temperature of the main circulation water, pressurein the tank and material temperature in the tank; E, stopping the leading of auxiliary steam, main steam, auxiliary circulation water and main circulation water, emptying till pressure in the tank isequal to environment pressure, and filtering. The method realizes purification of the titanium sulfate solution, and improves the crystallization efficiency of ferrous sulfate in the titanium sulfatesolution.