The invention discloses an NBT-based lead-free
ceramic material with low
dielectric loss and frequency stability and a preparation method thereof, the method comprises the following steps: according to a stoichiometric formula (1-x) Na < 0.465 > Li < 0.07 > Bi < 0.465 > Ta < 0.07 > Ti < 0.93 > O < 3-x > BaNd2Ti4O12, x is greater than or equal to 0.01 and less than or equal to 0.05, weighing Na < 0.465 > Li < 0.07 > Bi < 0.465 > Ta < 0.07 > Ti < 0.93 > O < 3 >
powder and BaNd2Ti4O12
powder, and uniformly mixing to form a full ingredient; carrying out ball milling,
drying and sieving on the full ingredients to form sieved materials; and pressing the sieved material into a
green body, and
sintering the
green body to obtain the NBT-based lead-free
ceramic with low
dielectric loss and frequency stability. The invention relates to the field of functional
ceramic materials, and solves the problems of high
dielectric loss and
high frequency sensitivity of pure NBT ceramic, the addition of a BNTO phase can inhibit abnormal growth of NBT grains and promote formation of a fine and uniform
microstructure, the
fine grain structure means that the
grain boundary area is greatly increased, and the BNTO phase has a good dielectric property. The increased
grain boundary can effectively adsorb and block migration of charge carriers (such as
oxygen vacancies), and the carriers are captured at the
grain boundary and are difficult to migrate for a long range, so that the
conductivity loss and the interface polarization loss are remarkably reduced.