According to the silver-
bismuth-
copper alloy electrode material for the high-temperature
crystal oscillator and the high-temperature-resistant
coating method for the
crystal oscillator, the problems that pure silver is prone to
crystal grain growth and oxidation to form
electrode material defects, and
frequency drift is caused by
electrode material defects of a traditional
crystal oscillator in a high-temperature environment are solved; a multi-element
alloy electrode material which takes silver as a basis and is added with
bismuth,
copper,
indium,
lanthanum and
antimony and a matched preparation and
coating process are provided, silver ensures excellent
conductivity of an electrode,
bismuth pinns a
grain boundary,
copper forms second-phase particles to jointly inhibit
grain growth at high temperature, and the
conductivity of the electrode is improved.
Indium preferentially forms a compact
oxide film,
lanthanum purifies impurities and refines initial crystal grains,
antimony optimizes wettability of a film layer to synergistically inhibit oxidation, and because crystal
grain growth is inhibited, a fine and uniform
microstructure of the electrode film layer can be maintained, uniform
electron scattering and stable resistance are ensured, and
electric field change of an excitation substrate caused by resistance fluctuation is avoided. The oxidation inhibition can prevent irregular change of electrode
mass and volume and local difference of
thermal expansion coefficient, and reduces
frequency drift of the
crystal oscillator.