145 results about "Ti 6al 4v" patented technology

There is provided an α-β type titanium alloy having a normal-temperature strength equivalent to, or exceeding that of a Ti-6Al-4V alloy generally used as a high-strength titanium alloy, and excellent in hot workability including hot forgeability and subsequent secondary workability, and capable of being hot-worked into a desired shape at a low cost efficiently. There is disclosed an α-β type titanium alloy having high strength and excellent hot workability wherein 0.08-0.25% C is contained, the tensile strength at room temperature (25° C.) after annealing at 700° C. is 895 MPa or more, the flow stress upon greeble test at 850° C. is 200 MPa or less, and the tensile strength/flow stress ratio is 9 or more. A particularly preferred α-β type titanium alloy comprises 3-7% Al and 0.08-025% C as α-stabilizers, and 2.0-6.0% Cr and 0.3-1.0% Fe as β-stabilizers.

Ferrules made of nano-titanium for incorporation into feedthrough filter capacitor assemblies are described. The feedthrough filter capacitor assemblies are particularly useful for incorporation into implantable medical devices such as cardiac pacemakers, cardioverter defibrillators, and the like, to decouple and shield internal electronic components of the medical device from undesirable electromagnetic interference (EMI) signals. Nano-titanium experiences significantly less grain growth after high temperature brazing in comparison to commercially pure (CP) titanium and the titanium alloy Ti-6Al-4V. For that reason, nano-titanium is an ideal material for use in implantable medical applications where high strength, structural integrity even after heating and corrosion resistance are desired.

The invention relates to bar material forging machining method of titanium alloy, particularly to a forging machining method of large-sized bar materials of TC4 (Ti-6Al-4V) titanium alloy. The forging machining method is characterized by comprising the following steps of step 1, performing cogging forging, step 2, performing intermediate forging above a phase transformation point, step 3, performing intermediate forging below the phase transformation point, step 4 and step 5, performing finished product forging and obtaining the phi 200 to 300 mm and 2000 to 3000 mm length of large-sized bar materials of the TC4 titanium alloy finally. Compared with the prior art, a large-sized ingot casting and a large-tonnage forging device are not required and the industrialized production can be achieved through an ordinary industrial 3 ton ingot and a small-tonnage forging press and the equipment investment is small, only a 3 tons of electric arc furnace and a 3000 tons of forming oil press which is matched with the electric arc furnace need to be invested in the phi 600 of 3 ton ingot, the small-tonnage forging press such as a 1600 tons of forging press needs to be invested in the forging process, and accordingly the equipment investment is significantly reduced.

The invention discloses a low-cost and high-strength titanium alloy. The alloy is to mix a Al-V or Fe-V intermediate alloy, electrolytic chromium, pure titanium or titanium alloy decoration shavings, industrial iron and titanium sponge to press electrodes according to the designed compositions and to be cast into an alloy pig through secondary smelting by a general vacuum consumable electrode arc furnace. The compositions by weight percent of the alloy are 4 to 6 percent of aluminum, 1.9 to 2.9 percent of vanadium, 1 to 3 percent of chromium, 1 to 3 percent of iron, and the balance being titanium and unavoidable impurities. Compared with a Ti-6Al-4V alloy and the prior high strength titanium alloy, the low-cost and high-strength titanium alloy has the advantages that the alloy has high plasticity under the condition that high strength is guaranteed; the cost of the alloy is lower than that of the Ti-6Al-4V; the hot workability of the alloy is good; and the alloy is easy to produce and is suitable for the requirements of various application fields on the low-cost and high-strength titanium alloy.

The invention aims to provide an anti-infective medical titanium alloy. Based on the chemical components of existing medical titanium alloy Ti-6Al-4V, a proper amount of element copper is added. After a special antibacterial heat treatment, a titanium copper phase is precipitated in the substrate of the medical titanium alloy, thus endowing the medical titanium alloy an anti-bacterial infection function. The titanium alloy can be widely applied to various titanium alloy medical equipment used in departments of orthopedics, stomatology and other medical clinical fields, thus solving the problems of bacterial infection and the like caused by implantation of medical titanium alloy medical equipment in current clinical practice.

The invention belongs to the technical field of alloys, and relates to a low-cost alpha and beta-type titanium alloy. The alloy is characterized by comprising the following components in percentage by weight: 3 to 3.7 percent of Al, 2.5 to 4 percent of Mo, 2 to 4 percent of Zr, 0 to 0.35 percent of Si, 2.3 to 3.3 percent of Cr or 0.4 to 1.2 percent of Fe, and the balance of Ti; the total amount of the impurity elements in the alloy is less than or equal to 0.4 percent, and the interstitial impurity element C is less than or equal to 0.04 percent; and the alloy comprises the following impurityelements: less than or equal to 0.04 percent of C, less than or equal to 0.15 percent of O, less than or equal to 0.04 percent of N, and less than or equal to 0.015 percent of H. Expensive vanadium element is substituted by using other metals with low prices in the alpha and beta-type titanium alloy, so the production cost of the alloy is reduced. Because the comprehensive mechanical property of the alpha and beta-type titanium alloy is equivalent to that of Ti-6Al-4V, the alpha and beta-type titanium alloy has higher cost performance and broad engineering application prospect.

This invention discloses a beta-type Ti alloy with low elastic modulus for mrdical application. The Ti alloy comprises: Nb 30-37%, Zr 0-20%, and Ti. The cast structure of the Ti alloy is beta phase. The Ti alloy has moderate strength, and can satisfy the strength requirement for clinical bearing material. The elastic modulus of the Ti alloy is only 45-55% that of Ti-6Al-4V alloy. The alloy is a casting alloy, and has no noble metals added such as Ta, thus effectively lowering the cost. Besides, all the added elements have biocompatibility, and toxic elements are avoided. The Ti alloy has high biocompatibility and mechanical compatibility, and can be used to produce bone plates with reduced stress shielding effect.

The invention relates to a preparation method of a TiBw/Ti-6Al-4V composite bar adopting a quasi-continuous reticular structure and solves problems that existing Ti-6Al-4V composites are harsh in technological condition, high in equipment requirement, low in production efficiency, difficult to produce on a large scale and the like. The method comprises steps as follows: low-energy ball milling and mixing are performed on spherical Ti-6Al-4V powder and TiB2 powder firstly; then TiB2/Ti-6Al-4V mixed powder is placed in a metal sheath for cold press molding, and vacuum degassing and sheath sealing welding are performed to obtain an extrusion billet; finally, short-time pre-sintering is performed on the obtained extrusion billet, and hot extrusion deformation is performed on the pre-sintered extrusion billet to obtain a required material. The method can be applied to preparation of a TiBw/Ti-6Al-4V composite adopting the quasi-continuous reticular structure.

The invention relates to a large-scale processing method of Ti-6Al-4V titanium alloy rod bars with the phi of 200-400mm and the length of over 3000mm. The technique is characterized by adopting Ti-6Al-4V titanium alloy casting ingots with the phi of 700-950 mm, a gas furnace for heating and heat preserving at 1150 DEG C, a hydraulic press for hammer cogging, and adopting multi-heating number smithing over the beta transition temperature with the whole smithing ratio not smaller than 3; heating and smithing below the beta transition temperature by 20-30 DEG C with a smithing ratio of 1.5-1.8; preserving the heat for 0.5-3 hours over the beta transition temperature by 20 DEG C, water cooling, performing homogenization treatment; finally heating below the beta transition temperature by 30-50 DEG C, performing multi-heating number smithing in the alpha+beta phase section to the finished product format and the total forging ratio of the alpha+beta phase section being not less than 6. The weight of a single rod bar is greatly improved through integral smithing of casting ingots/large-scale smithing stocks, the length of the rod bar can reach more than 3 m and the rod bars have favorable tissue and performance.

The present invention relates to a bone substituted material. Said bone substitute material is dicalcium silicate coating layer deposited on the surface of titanium alloy of Ti-6Al-4V, said coating layer is formed from beta-Ca2SiO4 and glass phase, and its thickness if 50-400 micrometers. Its preparation method incldues the following steps: firstly, synthesizing gamma-Ca2SiO4, then using atmospheric plasma spraying process to deposit the dicalcium silicate coating layer on the titanium alloy base body, and the combination strength of said coating layer and base body is greater than 34-40 MPa.The tests show that the bone apatite can be formed on the surface of dicalcium silicate, and cell can quickly grow and proliferate on the beta-Ca2SiO4 coating layer surface, so that said substitute material possesses good biological activity and compatibility.

The invention discloses a low-cost alpha plus beta type titanium alloy, which consists of 4.5-8 percent of aluminum, 0.3-3 percent of chromium, 0.3-2 percent of iron, and the rest of titanium and inevitable impurities by weight percent, wherein 0-3 percent of molybdenum, 0-3 percent of tin or 0-3 percent of zirconium can also be included. The alpha plus beta type titanium alloy of the invention has low cost of constituent elements and high comprehensive mechanical performance equivalent to Ti-6Al-4V, thus not only reducing the production cost of the titanium alloy, but also improving the cost performance. Therefore, the low-cost alpha plus beta type titanium alloy has wide market prospect.

The invention discloses boron-containing titanium alloy powder for additive manufacturing and a preparation method thereof and belongs to the technical field of titanium alloy materials. The boron-containing titanium alloy powder comprises the chemical components of, by weight, 4.5%-5.5% of Al, 3.5%-4.5% of V, 0.05%-1% of B and the balance Ti and inevitable impurity elements. Compounding is conducted according to the required alloy components, raw materials such as titanium boride and titanium sponge are mixed evenly and then pressed into an electrode; the electrode is subjected to vacuum consumable smelting into an ingot; and the ingot is forged into a bar, and then the bar is prepared into the titanium alloy powder through a non-crucible induction melting gas atomizing method. The detection result of the structural performance of a member manufactured by adopting the boron-containing titanium alloy powder shows that compared with existing Ti-6Al-4V powder, the boron element is addedso that cylindrical crystals caused by the temperature gradient in the additive manufacturing process can be weakened significantly, meanwhile crystal grains can be refined, and the mechanical performance of a material is improved.

A method for superplastically forming and/or diffusion bonding a structural member and an associated structural member are provided. The structural member is formed at least partially of titanium, e.g., Ti-6Al-4V, and has a fine grain structure. For example, the grain size of the material of the structural member can be less than 2 micron. The member can be superplastically formed and/or diffusion bonded at a reduced temperature, thereby potentially reducing the thermal energy required for forming and bonding, and also reducing the effects of heating on the structural member and the forming apparatus. In addition, the structural member can be formed at an increased strain rate.

The invention discloses a low-cost Alpha+Beta type titanium alloy, the titanium alloy contains, in weight percent: aluminum 4.5 to 8 percent, chromium 0.3 to 2 percent, iron 0.3 to 2 percent, molybdenum 0 to 1 percent, balance titanium and unavoidable impurities. The Alpha+Beta type titanium alloy of the invention contains no noble metal of vanadium, and has equivalent comprehensive mechanical properties compared with Ti-6Al-4V, thereby increasing the price performance ratio while reducing the titanium alloy manufacturing cost, and having the broad market prospect.

The invention relates to a medical high-strength Ti-6Al-4V alloy wire and a preparation technique and application thereof and belongs to the technical field of metal material preparation. The medical high-strength Ti-6Al-4V alloy wire comprises, by mass, 5.9%-6.3% of Al, 4.0%-4.3% of V, 0.10%-0.16% of O, 0.14%-0.22% of Fe and the balance Ti. The preparation technique comprises the steps of smelting, forging, two times of large-deformation rolling, cold drawing, intermediate annealing, temperature-control hot drawing, stress relief annealing of a semi-finished product, one-pass cold drawing, straightening and cutting-off, stress relief annealing, polishing and obtaining of a finished product. The medical high-strength Ti-6Al-4V alloy wire and the preparation technique and application thereof have the beneficial effects that the Ti-6Al-4V alloy wire is prepared through the technical process that heat machining, cold drawing and temperature-control hot drawing are combined, and the Ti-6Al-4V alloy wire has the advantages that the mechanical performance is high, the dimensional precision is high, the surface smoothness is high, and the structure property uniformity is good.

The invention provides a preparation method for a Ti-6Al-4V alloy part. A mixture of spherical Ti-6Al-4V alloy powder, nonspherical Ti-6Al-4V alloy powder and a catalytic degreasing binder is subjected to banburying at the protective atmosphere, the material obtained through banburying are pelletized, and then alloy feed is obtained; the alloy feed is sequentially subjected to injection molding and pressure maintaining, and an alloy part forming blank is obtained; at the protective atmosphere, the alloy part forming blank is subjected to degreasing, and a presintering body is obtained; and under the vacuum condition, the presintering body is subjected to sintering, and after cooling, the Ti-6Al-4V alloy part is obtained. According to the alloy part obtained through the method, the tensilestrength can reach 765 MPa, and the bending strength can reach 1,145 MPA. Alloy parts in complex shapes can be prepared.

The invention relates to a low-cost and high-performance titanium alloy and a preparation method thereof. The alloy is a quaternary titanium alloy which is formed by taking titanium as a main body element and additionally adding three elements. The alloy comprises the following components in percentage by mass: 1-5% of Fe, 0.1-0.4% of O, 0.1-0.3% of B and the balance of titanium and inevitable impurities. The preparation method comprises the following steps: adding the raw materials into a suspended smelting furnace of a cold crucible where argon is introduced in a designed alloy component proportion; repeatedly smelting for several times to obtain cast ingots; cogging and forging the cast ingots above the phase transformation point to form sheared billets; then rolling the sheared billet to form rods; thermally treating the sampled rods; and finally representing structure and performance of the rods. The preparation process is simple in method, and the prepared alloy is uniform in component. The tensile strength reaches over 950MPa, the ductility is not less than 15%, and the percentage reduction of area is not less than 25%. The basic mechanical property of the alloy is equivalent to that of Ti-6Al-4V but the cost has the advantage of over 15% compared with that of the Ti-6Al-4V. The alloy can replace part of titanium alloys which are relatively high in price in some fields.

The invention discloses a preparation method of a double-scale crystalline grain Ti-6Al-4V material. The preparation method adopts a forming way combining a high energy ball milling process with a spark plasma sintering process, and comprises the following steps of: firstly, taking powder in a segmentation manner in the whole high energy ball milling process to obtain powder with different refining degrees, wherein the grain size distribution range of the ultrafine crystal powder is controlled to be between 100nm and 1 mu m, and the grain size distribution range of the nanocrystalline powder is controlled to be between 10nm and 100nm; then, compounding and uniformly mixing one of the powder serving as the raw material and the ultrafine crystal powder with the nanocrystalline powder according to any mass ratio; and finally, optimizing the spark plasma sintering process. By controlling the mixing proportion of the two powder, the proportion of a rough crystal zone and a fine crystal area in a double-scale crystalline grain Ti-6Al-4V material tissue can be accurately controlled, and the defect that the proportion of rough and fine crystals are difficult to be accurately controlled is overcome; and meanwhile, by optimizing the sintering parameters of the spark plasma sintering process, the material has an excellent comprehensive mechanical property.

A medical biologicl body to be transplanted in human body is prepared from a 4-element (Ca-Si-P-Mg) glass paint and a Ti alloy (Ti-6Al-4V) substrate through depositing said glass paint on the surface of Ti alloy substrate. Said glass paint contains micro crystals of calcium phosphate and calcium silicate, and has high bioactivity and biocompatibility.

Alloys of titanium with 20-22 at. % niobium and 12-13 at. % zirconium. The alloys are prepared by mechanical alloying of elemental powders and densification by spark plasma sintering. The alloys have a nano-scaled, equiaxed granular structure, a microhardness of at least 650 HV and a modulus of 90-140 GPa. The inventive alloy is corrosion resistant, biocompatible, and is of a higher wear resistance and durability compared to the Ti-6Al-4V alloy. The bioactive surface of the inventive nanostructured alloy promotes a higher protein adsorption that stimulates new bone formation than other titanium-based alloys. These alloys are suitable for various biomedical and dental applications.

The invention discloses a method for utilizing boron alloying metamorphism to reduce anisotropy of TC4 additive manufacturing. The method includes the following steps of S1, drying Ti-6Al-4V-0.05B alloy powder under a vacuum environment at 120 DEG C for 8 hours; S2, using a laser additive manufacturing device for conducting laser melting, covering and forming on the alloy powder dried in step S1 under a protective atmosphere of inert gas to obtain a formed sample component; S3, conducting thermal dissolution and aging treatment on the formed component under argon protection of the inert gas. By using a new material obtained by alloying boron and TC4 in the method for laser melting, covering and sedimentation, boron effectively inhibits generation of thick preliminary cylindrical crystals in a TC4 titanium alloy during forming and facilitates isometry and refining of TC4 titanium alloy grains, the structure is more uniform, and the anisotropy of conventional mechanical performance is controlled within 10%. A new approach is provided for laser additive manufacturing of the TC4 titanium alloy.

The invention discloses a method for manufacturing a titanium alloy thick-wall pipe, which is suitable for thermal stretching manufacture of a Ti-6Al-4V titanium alloy thick-wall pipe. The method is characterized by comprising the following steps: (1) preparing a blank; (2) heating the pipe blank; (3) thermally stretching the pipe blank; (4) thermally scalping the pipe blank; (5) thermally straightening the pipe blank; (6) polishing a surface oxidation film; (7) fixing the size and blanking the pipe blank; and (8) polishing the pipe blank to obtain a qualified product. The method for producing the Ti-6Al-4V titanium alloy thick-wall pipe by adopting a new thermal stretching process overcomes the defect of the traditional drilling method, and has the characteristics of quick efficiency, good material, high yield and the like.