The invention relates to a compound production method, particularly to a synthesis method and apparatus of hexahydric cyclocompounds by using a continuation method. Dienophile and diene mixtures are added in a multi-segment tubular reactor according to a mol ratio of 1-2:1 to perfrom reaction, the reaction temperature of a first segment is controlled in 50-200 DEG C, the cycle ratio is circulation:discharge=15:1, the discharged portion enters into a second segment of reactor, the temperature is controlled in 100-300 DEG C to perform reaction, the cycle ratio is 5:1, the discharged portion enters into a third segment of reactor, the temperature is controlled in 150-350 DEG C to perform reaction, the discharged material of the end reactor is separated, cooled and then materials are educed to be rectified so as to obtain products, the non-reacted materials is cycled to continue reaction. The invention improves the reaction conversion rate and safty performance, largely reduces energy consumption, enhaces product quality and yield, ensures subsequent product quality.