The invention relates to outer wall composite nano paint. The outer wall composite nano paint consists of the following raw materials: nano composite material II, plasticizing agent, pure water, dispersant, antifreeze, defoaming agent, nano titanium dioxide, flatting agent, styrene-acrylic emulsion, fine particle calcium carbonate and coarse whiting, thickening agent and film forming additive, wherein based on the total weight of inner wall nano paint, the outer wall composite nano paint comprises 7.2 percent of the nano composite material II, 2.8 percent of the intensifier, 0.3 percent of the dispersant, 2.6 percent of the antifreeze, 0.3 percent of the defoaming agent, 26 percent of the nano titanium dioxide, 0.6 percent of the flatting agent, 33 percent of the styrene-acrylic emulsion, 8 percent of the fine particle calcium carbonate and coarse whiting, 1 percent of the thickening agent, 2.2 percent of the film forming additive, and the balance being pure water. The outer wall composite nano paint integrates the functions of heat insulation, fire retardation, heat preservation, environment protection, high elasticity and impact resistance.