The invention provides a method for treating
coking wastewater hardness removal resin regeneration waste liquid by using an old membrane, and belongs to the technical field of
coking wastewater zero
discharge treatment, and the method comprises the following steps: step 1), carrying out high-flow washing on an old
reverse osmosis membrane, and then introducing a
test solution to test the
salinity of the old
reverse osmosis membrane, marking the old
reverse osmosis membrane with
low salinity as a low-
salinity membrane according to the
salinity, introducing a
sodium hypochlorite solution into the old reverse
osmosis membrane with high salinity to carry out circular oxidation until the
desalination rate reaches a preset value, and marking the old reverse
osmosis membrane after oxidation treatment as a high-salinity membrane for later use; (2) adding
sodium hydroxide and
sodium carbonate into the
hardness-removed resin regeneration waste liquid, stirring, dehydrating chemical
sludge generated by reaction, introducing supernate after reaction into the high-salt-permeability membrane obtained in the step (1), refluxing concentrated water of the high-salt-permeability membrane, and continuously adding
sodium hydroxide and
sodium carbonate; and (3) introducing the high-salt-permeability membrane
produced water obtained in the step (2) into the low-salt-permeability membrane obtained in the step (1), conveying the low-salt-permeability concentrated water out of the
system, carrying out ultrahigh-pressure concentration or extracting sodium
chloride by an evaporative
crystallization system, applying the low-salt-permeability membrane
produced water to high-flow flushing and test liquid preparation in the step (1), and delivering redundant low-salt-permeability membrane
produced water as product water. According to the invention, the
impact problem after the
hardness removal resin regeneration waste liquid flows back to the
water treatment system can be eliminated, and meanwhile, a new
resource utilization mode of the old reverse
osmosis membrane is expanded.