The invention belongs to the technical field of concrete shear walls, and particularly relates to a precast sandwich insulation laminated concrete shear wall and a preparation method and application thereof. The concrete shear wall includes a precast concrete wallboard, vertical rebars in a wall, transversely distributed rebars in the wallboard, steel plates, web member rebars, lower chord rebars,support vertical bars, support transverse bars, post-pouring concrete and an insulation layer, the precast concrete wallboard is composed of an outer leaf precast concrete wallboard and an inner leafprecast concrete wallboard, and the vertical rebars in the wall, the transversely distributed rebars in the wallboard, the steel plates, the web member rebars, the lower chord rebars, the support vertical bars and the support transverse bars together form steel triangular truss floor bearing plates; and the outer leaf precast concrete wallboard, the insulation layer, the steel triangular truss floor bearing plates and the inner leaf precast concrete wallboard are connected successively, and the space between the steel triangular truss floor bearing plates form the area for the post-pouring concrete. The shear wall can ensure that the phenomenon of mold swelling does not occur when pouring concrete in a middle cavity.