The application discloses a preparation process of a surface composite protective
coating of a
neodymium-iron-
boron magnet. The process utilizes the magnetostrictive effect of the
magnet to drive the
coating densification, comprising: providing a magnetized sintered
neodymium-iron-
boron magnet;
coating a precursor coating containing low-melting-point
metal alloy nanoparticles and
graphene nanosheets; placing the magnet in an alternating
magnetic field, and through three-stage variable-frequency vibration densification treatment, i.e. low-frequency driving macroscopic flow leveling, medium-frequency utilizing the intrinsic relaxation of the
particle system to realize quasi-
resonance rearrangement, and high-frequency driving pore collapse and interface
diffusion, the
porosity of the coating is reduced to below 1%, and the
magnetic field strength is limited to 0.02-0.1 times the intrinsic coercive force of the magnet to ensure that the magnetic performance is not damaged; supplemented by semi-
solid thixotropic heating,
pulse current flash
sintering and
silane hole sealing treatment. The obtained
composite coating has a gradient dense structure, the
porosity is less than 1%, the interface
shear strength is more than 30 MPa, the irreversible
magnetic flux loss of the magnet substrate is less than 2%, and the process is green and simple.