35results about How to "Strong liquid absorption and retention capacity" patented technology

The invention discloses a graphine composite electric conduction agent for an iron phosphate lithium battery, and simultaneously discloses a preparation method of the electric conduction agent. The electric conduction agent provided by the invention consists of graphine, active carbon and a bonding agent in a weight ratio of 1:(0.001-0.1):(0.01-1). The preparation method comprises the following steps: 1) preparing a solution A; 2) preparing a solution B; and 3) preparing the electric conduction agent. According to the invention, the preparation method is simple, the prepared electric conduction agent has the advantages of uniform dispersion, good stability, high electron conduction capability and uniform heat conduction, and the electric conduction agent has higher liquid absorption and liquid protection capabilities when being doped into the iron phosphate lithium battery; and the electric chemical property of the iron phosphate lithium battery which is prepared by adopting the electric conduction agent provided by the invention is improved prominently, compared with the iron phosphate lithium anode material in which the composite electric conduction agent is not doped, when the prepared graphite composite electric conduction agent is doped into the 50AH iron phosphate lithium anode material, the alternating current internal resistance is reduced by 20%, and the circulating service life is improved by 15%.

The invention discloses an asphalt-based nanoporous carbon material, a negative material thereof, and a lithium ion battery. The asphalt-based nanoporous carbon material is prepared by mainly using 0.1-10g of asphalt, 3-50g of anhydrous aluminum trichloride, 100-400ml of anhydrous carbon tetrachloride and 200-500ml of a reaction terminating agent, and the amounts of the above raw materials can be freely adjusted in proportion. The asphalt-based nanoporous carbon material is prepared by mainly using asphalt, anhydrous aluminum chloride, anhydrous carbon tetrachloride and the reaction termination agent, and asphalt and anhydrous carbon tetrachloride undergo a Friedel-Crafts crosslinking reaction through a nanometer pore forming technology, so the obtained asphalt-based carbon material has a porous structure and a high specific surface area, and the negative material prepared by using the asphalt-based nanoporous carbon material has the characteristics of strong electrolyte imbibition and retention ability, good processing performance, low price and the like, and can greatly improve the cycle performances of the lithium ion battery.

The invention relates to a graphene composite conductive agent and a preparation method thereof. The graphene composite conductive agent is prepared from the following components in parts by weight: 70-100 parts of graphene, 20-45 parts of carbon nano-tubes, 30-45 parts of epoxy resin, 10-25 parts of monoethanolamine, 200-300 parts of solvent, 2-3 parts of additives, 7-10 parts of conductive polymer agent, 2-4 parts of glass beads and 3-8 parts of iridium acetylacetonate. According to the conductive agent and the method, the graphene is taken as the master component, the carbon nano-tubes are taken as the secondary component, through utilization of the excellent electric conductivity of the graphene, the capacity of an electrode material is increased, the internal resistance of a battery is reduced, and the cycle life of the battery is prolonged. The 2C rate is improved by 6-10% when a lithium ion battery is prepared, the cost is reduced, and the lithium ion battery is highly competitive.

The invention relates to a lithium battery, a silicon composite material for the same and a method for preparing the silicon composite material, and belongs to the technical field of lithium batteries. The silicon composite material for the lithium battery is provided with core-shell structures. Silicon particles are used as cores, shells comprise middle layers and outer layers, the middle layersare coated on the surfaces of the silicon particles, the outer layers are coated on the surfaces of the middle layers, the middle layers comprise non-electronic conductive high-polymer materials, theouter layers comprise inorganic lithium compounds, and the inorganic lithium compounds are a type of LiBH4, Li3N, Li2NH, LiBNH6 and Li1.8N0.4Cl0.6; a thickness ratio of the middle layers to the outerlayers is 1-5:1-5. The lithium battery, the silicon composite material and the method have the advantages that the non-electronic conductive high-polymer materials and the inorganic lithium compoundsare coated on the surfaces of the particles made of silicon materials, the quantities of lithium ions can be increased by the inorganic lithium compounds coated on the surfaces of the particles made of the silicon materials in charge and discharge procedures, and accordingly the first efficiency, the specific capacity and the cycle performances can be improved.

The invention discloses an anode material for a lithium-ion power battery and a preparation method of the anode material, and relates to the field of preparation of battery materials, in particular tothe field of preparation of the anode materials of lithium batteries. The anode material is characterized by being prepared from porous silicon dioxide and coating compound asphalt, wherein porous silicon dioxide is prepared from raw materials as follows: polycrystalline silicon powder, hydrochloric acid, silver carbonate, hydrofluoric acid and hydrogen peroxide; the compound asphalt is preparedfrom materials as follows: nano calcium carbonate, asphalt, graphene, sodium hydroxide, a binder and distilled water; after porous silicon dioxide and the compound asphalt are mixed uniformly in a ratio being 5:(3-5), a mixture is carbonized, and a silicon-carbon anode material is prepared. The prepared silicon-carbon composite material has the effect of improving rate performance and safety performance while the transfer number of lithium ions is increased and stacking of the lithium ions is reduced, further has advantages of high gram volume, excellent cycle performance, high liquid absorption and retaining capability, low cost and low expansion rate, and is particularly suitable for meeting demands of high-energy-density batteries for the anode material.

Provided is a method for preparing a high-energy-density negative pole piece and a lithium ion battery comprising the high-energy-density negative pole piece. By weight, the preparation method comprises the following steps of 1 preparation of negative pole high-viscosity slurry, 2 preparation of modified nickel foam and 3 rolling. According to the high-energy-density negative pole piece and the preparation method of the lithium ion battery of the high-energy-density negative pole piece, the contact internal resistance of electrode active matter and a current collector is effectively reduced, and the comprehensive performance of an electrode is improved. Meanwhile, the surface of the nickel foam is plated with lithium ion containing matter, and therefore the transmission rate of lithium ions in the charging and discharging process can be increased. The advantages of being high in energy density, high in liquid absorption capacity, high in adhesive power and the like are achieved, and the high-energy-density negative pole piece is especially suitable for the lithium ion batteries used in the digital field.

The invention discloses a graphine composite electric conduction agent for an iron phosphate lithium battery, and simultaneously discloses a preparation method of the electric conduction agent. The electric conduction agent provided by the invention consists of graphine, active carbon and a bonding agent in a weight ratio of 1:(0.001-0.1):(0.01-1). The preparation method comprises the following steps: 1) preparing a solution A; 2) preparing a solution B; and 3) preparing the electric conduction agent. According to the invention, the preparation method is simple, the prepared electric conduction agent has the advantages of uniform dispersion, good stability, high electron conduction capability and uniform heat conduction, and the electric conduction agent has higher liquid absorption and liquid protection capabilities when being doped into the iron phosphate lithium battery; and the electric chemical property of the iron phosphate lithium battery which is prepared by adopting the electric conduction agent provided by the invention is improved prominently, compared with the iron phosphate lithium anode material in which the composite electric conduction agent is not doped, when the prepared graphite composite electric conduction agent is doped into the 50AH iron phosphate lithium anode material, the alternating current internal resistance is reduced by 20%, and the circulating service life is improved by 15%.

The invention relates to a graphene conductive agent. The graphene conductive agent is prepared from the following components in parts by weight: 120-150 parts of graphene, 30-45 parts of nonylphenoxypoly(ethyleneoxy)ethanol, 10-25 parts of monoethanolamine, 200-300 parts of solvent, 2-3 parts of additives, 7-10 parts of conductive polymer agent, 2-4 parts of glass beads and 3-8 parts of iridium acetylacetonate. According to the conductive agent, the graphene is taken as the master component, through utilization of the excellent electric conductivity of the graphene, the capacity of an electrode material is increased, the internal resistance of a battery is reduced, and the cycle life of the battery is prolonged. The 2C rate is improved by 6-10% when the lithium ion battery is prepared, the cost is reduced, and the lithium ion battery is highly competitive.

The invention relates to a lithium ion battery graphene conductive agent and a preparation method thereof. The graphene conductive agent comprises the following components by mass: 25-30 parts of graphene, 10-15 parts of polyethylene glycol, 5-10 parts of monoethanolamine, 100-160 parts of a solvent, 1-5 parts of a rare earth element, and 0.5-1 part of titanium carbide. According to the invention, the graphene conductive agent utilizes the excellent conductivity of graphene to enhance the capacity of an electrode material, reduce the battery internal resistance, and improve the battery cycle life. The dosage of the graphene conductive agent only accounts for 50-60% of that of existing conductive agents during preparation of a lithium ion battery, the binder dosage is reduced by 18%, and the 2C multiplying power is improved by 6-10%, the cost is saved, and the lithium ion battery can be more competitive.

The invention relates to a silicon-carbon composite negative electrode material. The silicon-carbon composite negative electrode material has a core-shell structure and comprises an inner core part and a shell part coated on the inner core part, wherein the inner core part is nano silicon, and the shell part is a composite structure containing a porous carbon material and a lithium salt. The invention further provides a preparation method of the silicon-carbon composite negative electrode material.

The invention discloses a graphene conductive agent. The internal composition components of the graphene conductive agent include, by mass, 17-22 parts of graphene, 6-9 parts of polyacrylonitrile fibers, 2-5 parts of triethylenetetraamine, 4-6 parts of activated carbon, 120-150 parts of an adhesive solvent, 2-4 parts of rare earth oxide and 0.75-1 part of titanium carbide. The graphene conductiveagent using the excellent conductivity of the graphene improves the capacity of an electrode material, reduces the internal resistance of a battery, prolongs the cycle life of the battery and saves the cost, so the lithium ion battery is competitive, and has strong electron conduction ability and uniform heat conduction, and the graphene conductive agent has strong liquid absorbing and preservingability when doped into the lithium ion battery.

The invention relates to a high temperature-resistant lithium ion battery composite diaphragm. The composite diaphragm has a skin / core / skin three-layer composite membrane structure. The skin layer includes high-density polyethylene. The core layer includes a mixture of low-density polyethylene and an inorganic filler. The composite diaphragm is prepared from raw materials of the surface layers andthe core layer through co-extrusion casting based on a dry process. The invention also relates to a preparation method of the lithium ion battery composite diaphragm based on the dry process. The lithium ion battery composite diaphragm has good heat resistance.

The invention relates to a graphene composite conductive agent and a lithium ion battery prepared from same. The graphene composite conductive agent comprises the components as follows in parts by mass: 80-120 parts of graphene, 20-45 parts of acetylene black, 30-45 parts of nonylphenol polyoxyethylene ether, 10-25 parts of monoethanolamine, 200-300 parts of solvent, 2-3 parts of auxiliaries, 7-10 parts of conductive macromolecular agent, 2-4 parts of glass beads and 3-8 parts of iridium-acetylacetonate. The graphene composite conductive agent takes graphene as the main component and takes the acetylene black as the auxiliary component; due to the excellent conductivity of graphene, the capacity of the electrode material is improved, the internal resistance of the battery is lowered, and the cycling life of the battery is prolonged; and in addition, the 2C rate of the prepared lithium ion battery is improved by 6-10%, so that the cost is saved, and the prepared lithium ion battery is more competitive.

The invention relates to a preparation method of a composite conductive agent used in lithium ion batteries. The preparation method comprises an organic composite solvent preparation process, a water-based composite solvent preparation process and a composite conductive agent preparation process. Aniline, phenylacetylene, an organic lithium compound and an organic solvent are used in the organic composite solvent preparation process, ammonium persulfate, hydrochloric acid, acidized carbon nano tubes and a water-based solvent are used in the water-based composite solvent preparation process, and an organic composite solvent and a water-based composite solvent are used in the composite conductive agent preparation process. The organic lithium compound in the composite conductive agent can use lithium ions in the organic lithium compound to reduce lithium ions caused by SEI film loss in the charging and discharging process of the lithium ion batteries, and the cycle performance of the lithium ion batteries is improved, so that the composite conductive agent has the characteristics of high conductivity, large specific surface area and the like, and the liquid suction and liquid retaining capacity of the composite conductive agent is improved.

The invention relates to a high-power lithium-ion battery, which comprises a positive plate, a negative plate, a membrane and an electrolyte, wherein the lithium-ion battery comprises a graphene composite conductive agent; the high-power lithium-ion battery is evenly dispersed into a positive active material and a negative active material; and the graphene composite conductive agent is prepared from the following components in parts by mass: 120-150 parts of graphene, 20-35 parts of Super-p, 10-15 parts of carbon nanotubes, 30-45 parts of nonylphenol polyoxyethylene ether, 10-25 parts of monoethanolamine, 200-300 parts of solvents, 2-3 parts of assistants, 7-10 parts of conductive polymer agents, 2-4 parts of glass beads and 3-8 parts of acetylacetonate iridium. The graphene is taken as a main component and has excellent conductivity, so that the capacity of the electrode material is improved; the internal resistance of the battery is reduced; the cycle lifetime of the battery is prolonged; the cost is reduced; and the lithium-ion battery has higher competitiveness.

The invention relates to a graphene composite conductive agent and a preparation method thereof. The graphene composite conductive agent is prepared from the following components in parts by weight: 70-100 parts of graphene, 20-45 parts of carbon nano-tubes, 30-45 parts of epoxy resin, 10-25 parts of monoethanolamine, 200-300 parts of solvent, 2-3 parts of additives, 7-10 parts of conductive polymer agent, 2-4 parts of glass beads and 3-8 parts of iridium acetylacetonate. According to the conductive agent and the method, the graphene is taken as the master component, the carbon nano-tubes are taken as the secondary component, through utilization of the excellent electric conductivity of the graphene, the capacity of an electrode material is increased, the internal resistance of a battery is reduced, and the cycle life of the battery is prolonged. The 2C rate is improved by 6-10% when a lithium ion battery is prepared, the cost is reduced, and the lithium ion battery is highly competitive.

The invention provides a preparation method of a high-capacity silicon-carbon composite negative electrode material. The method comprises three preparation steps of a composite material A, a composite material B and the silicon-carbon composite negative electrode material, wherein polystyrene, a carboxylated carbon nano tube and nanosized silica spheres are used in the preparation process of the composite material A; the composite material A and a sucrose solution are used in the preparation process of the composite material B; an argon furnace and argon are used in the preparation process of the silicon-carbon composite negative electrode material; and the prepared silicon-carbon composite negative electrode material is doped with small-particle size silica in a large-particle size polystyrene gap, so that the contact area and the compaction density of the silicon-carbon composite material can be improved and the internal resistance of the silicon-carbon composite material is reduced. The silica is expanded in the charge and discharge processes, but the spherical polystyrene can buffer expansion of the silica. Meanwhile, the polystyrene has a double-bond structure, so that the transmission rate of electrons can be improved and the rate capability of the silicon-carbon composite negative electrode material is improved.

The invention discloses a lithium ion battery silicon composite negative electrode material and a preparation method thereof. The silicon composite negative electrode material comprises a matrix mixture and a carbon layer which is coated on the surface of the matrix mixture. The matrix mixture is composed of the following components in parts by weight: 1 to 5 parts of nano silicon, 1 to 5 parts of lithium-containing compound, 1 to 10 parts of hollow carbon sphere, and 70 to 95 parts of graphite. The capacity of the negative electrode material is increased by the nano silicon, the doped hollow carbon spheres reduce the expanding effect of silicon during the reaction process, and thus the conductivity and structure stability of the matrix material are both improved. The carbon layer, which is coated on the matrix surface, is used to connect different matrix parts. Each component in the matrix mixture cooperates with the carbon layer and generates a synergetic effect, so the silicon composite negative electrode material has the advantages of large capacity, strong ability of absorbing and maintaining liquid, low expansion rate, and good cycling performance, is capable of improving the comprehensive performance of lithium ion battery, and has a wind application prospect.

The invention belongs to the field of preparation of lithium-ion battery materials, and specifically relates to a preparation method of a nanoporous lithium-rich lithium iron phosphate material. At the same time, fully mix the lithium salt, phosphorus salt, and iron source at the atomic level, add lithium amide and stir evenly, then add the above lithium powder complex, then dissolve it in the glucose solution, stir evenly, and spray dry to obtain The precursor is dissolved in tetrahydrofuran to remove the polymer template and heat-treated to obtain a porous lithium-rich lithium iron phosphate composite material. In the present invention, the prepared nanoporous lithium-rich lithium iron phosphate material utilizes the lithium ions provided by the core lithium powder to improve the transmission rate, gram capacity and liquid absorption capacity of lithium ions in the charging and discharging process, and is applied to lithium ion batteries , has the characteristics of good rate performance and excellent cycle performance.

The invention discloses a nano electrode material of an energy storage lithium ion battery. The nano electrode material is prepared by the following method: 1) taking lithium carbonate as a lithium source; 2) taking tetrabutyl titanate as a titanium source; 3) adding carbon nanotubes into a mixed solution of acetic acid and nitric acid, and carrying out ultrasonic treatment to form a suspension; 4) mixing the solutions in an isopyknic manner, and continuously adding the suspension in the stirring process to form a viscous colloid; (5) standing for 12 hours in an environment with the relative humidity being lower than 40%, stirring, standing for 12 hours in an environment with the relative humidity being lower than 20%, and drying in a drying oven of 80-90 DEG C to form lumps; and 6) grinding the block into powder, sintering in a calcining furnace, cooling for solution treatment, sintering again, and cooling to room temperature to obtain the nano negative electrode material. The nano electrode material has the advantages of strong liquid absorption and retention capability, excellent cycle performance, improvement of the energy storage and utilization efficiency, and reduction of the environmental pollution.

A method for preparing a high specific energy negative pole piece and a lithium ion battery thereof, in parts by weight, comprising the following steps: 1) preparation of negative high-viscosity slurry; 2) preparation of modified nickel foam, and 3) pressing. The invention effectively reduces the contact internal resistance between the electrode active material and the current collector, improves the comprehensive performance of the electrode, and at the same time, the surface of the nickel foam is plated with a substance containing lithium ions, which can increase the transmission rate of lithium ions during charging and discharging. It has the advantages of high energy density, strong liquid absorption capacity, and strong adhesion, and is especially suitable for lithium-ion batteries used in the digital field.

The invention discloses a lithium ion battery silicon-carbon negative electrode material and a preparation method thereof. The negative electrode material comprises a core-shell structure, and a middle layer is arranged between the core and the shell. The core comprises a silicon material, the middle layer is a buffer layer composed of hollow carbon spheres, and the shell is a graphite-coated layer. The core comprises a silicon material, and thus the gram volume of the negative electrode material is increased. Moreover, the buffer layer composed of hollow carbon spheres relieves the silicon expansion, and the liquid absorbing and maintaining performance of the negative electrode material is also improved. The graphite coated layer has very good mechanical strength and conductivity. The materials in each layer cooperate with each other and generate a synergetic effect, so that the structure of the negative electrode material becomes more stable, and the structure is not easy to destruct during the discharge / charge process. The negative electrode material has the advantages of high gram volume, strong liquid absorbing and maintaining performance, and low expansion rate. The lithium ion battery using the negative electrode material has the advantages of high capacity maintaining rate during the circle process, slow attenuation speed, and excellent cycling performance, and is especially suitable for the field of mobile communication.

The invention relates to the technical field of lithium ion batteries, and provides an integrated lithium ion battery and a preparation method thereof in order to solve the problems of interface relaxation and structural failure caused by volume changes of traditional lithium ion batteries during charging and discharging. The lithium ion battery is composed of Janus separator and positive and negative electrode sheets. The polar functional layer is fixed with the negative electrode sheet, and the non-polar functional layer is fixed with the positive electrode sheet. In the present invention, the A surface of the Janus separator is designed as a polar surface, which is conducive to the formation of a stable and uniform SEI film on the surface of the negative electrode; the B surface of the Janus separator is designed as a non-polar surface, which ensures the development of the electrochemical performance of the positive electrode and facilitates the development of the positive electrode material. Higher capacity and rate capability.

The invention relates to the technical field of lithium-ion batteries. In order to solve the problem that the traditional lithium-ion battery separator easily causes a short circuit inside the battery and cannot meet the specific requirements of positive and negative electrodes, a Janus separator for lithium-ion batteries is provided. The Janus separator for lithium-ion batteries It consists of a high temperature resistant support layer and polar functional layers and nonpolar functional layers loaded on both sides of the high temperature resistant support layer. The Janus separator of the lithium ion battery of the present invention can promote the formation of a more stable and high-quality SEI film on the surface of the negative electrode, which is conducive to the higher capacity and rate performance of the positive electrode material, thereby improving the safety and high-temperature cycle performance of the battery.

The invention relates to a preparation method of the composite cathode material of a lithium ion battery, the composite cathode material of the lithium ion battery and the lithium ion battery and belongs to the technical field of lithium ion battery materials. The preparation method includes: dispersing silicon materials and polyacrylonitrile in a spinning solvent to obtain a core layer spinning solution, and dispersing polymethyl methacrylate in a spinning solvent to obtain a shell layer spinning solution; using the coaxial spinning technology to produce fibers so as to obtain a wrapping precursor; adding the wrapping precursor into a film-forming additive solution, mixing, and heating to remove the solvent so as to obtain a film-forming precursor; sintering the film-forming precursor under 500-800 DEG C for 1-24 hours to perform carbonization treatment so as to obtain the composite cathode material. The composite cathode material prepared by the method is high in gram volume, high in liquid absorbing and maintaining ability, excellent in circulation performance, high in low-temperature discharge ability, quite suitable for being applied to fields such as electric cars and energy storage, and the like.