The invention discloses a treatment system for removing benzenes in petrochemical industry waste gas. The system comprises a waste heat exchanger, a gas overheating protection device, a thermal type gas mass flow meter, a mixed gas flow control valve, a bag type dust collector, a tungsten coil surface activation-ozone oxidation treatment device, a smoke washing purifying tower, a draught fan and the like. According to the system, the unique surface activation property of ozone on the surfaces of some metal elementary substances is creatively utilized; when a tungsten metal coil is in an electrified incandescence state, ozone can rapidly release activated oxygen atoms on the surface of the tungsten metal coil, and a strong oxidation environment can be generated on the surface of tungsten metal; when molecules, containing C-C bonds with the conjugation effect, of benzenes and the like are in the strong oxidation environment, the conjugated C-C bonds of the molecules can be broken by the activated oxygen atoms, the molecules of benzenes can be decomposed into H2O, CO2 and other inorganic molecules finally under oxygenolysis, and thus the purpose of removing benzenes in waste gas is achieved.