The invention discloses and provides an electromagnetic shielding composite wallpaper, which is characterized in that the wallpaper is composed of the following layers from the inner to the outer: fiber gridding cloth and metal coated on the surface thereof 10, an inner adhesive layer 20, a micro-porous plastic layer 30, an outer adhesive layer 40, and decoration paper 50, wherein the layers are connected through an adhesive. The invention also provides a manufacturing method of the electromagnetic shielding composite wallpaper. The electromagnetic shielding composite wallpaper provided by the invention has an electromagnetic shielding function, has the characteristics of alkali resistance, weatherability, and good fire resistant performance, does not carry out chemical reactions with alkaline cement plaster, and can be widely applied to fields that needs heat insulation under cold, hot, and damp environment, such as machinery, electronics, construction, aviation, aerospace, automobiles, and naval vessels.