The invention relates to a polypropylene antistatic composite material and a preparation method thereof, belonging to the technical field of polypropylene composite materials. The invention is characterized in that the polypropylene antistatic composite material contains conductive aluminum borate whiskers, and is AlB[w]/PP for short. The preparation method comprises the following steps: proportionally adding aluminum borate whiskers into distilled water, adding concentrated hydrochloric acid so that the acid concentration reaches 0.6-1.2 mol.L<-1>, proportionally adding tin tetrachloride and urea, heating the mixed liquor to 90-110 DEG C, reacting for 1-3 hours, filtering, washing to remove unreacted substances, drying the filter cake, and calcining to obtain conductive aluminum borate whiskers (AlB[w] for short); and proportionally mixing the AlB[w] and polypropylene, mixing, crushing, putting the mixture in a die, putting the die in a muffle furnace at 180-200 DEG C, keeping the temperature for 30-60 minutes, carrying out die forming in a flat vulcanizing machine, and depressurizing and stripping when the temperature of the die drops to below 60 DEG C, thereby obtaining the AlB[w]/PP.